In a method of forming a liquid crystal display device, a black matrix is disposed on a substrate including a switching element formed thereon, a color filter is disposed on the switching element, a pixel electrode is electrically connected to the switching element, and a first alignment layer is disposed on the pixel electrode, to form a first substrate. A second substrate including a second alignment layer is formed. At least one of the first alignment layer and the second alignment layer includes a reactive mesogen. A liquid crystal layer is interposed between the first substrate and the second substrate. A light is irradiated onto the second substrate to provide pretilt angles of liquid crystal molecules of the liquid crystal layer.