Invention Grant
US09564274B2 Metal complex dye, photoelectric conversion element, dye-sensitized solar cell, dye solution, and compound
有权
金属络合染料,光电转换元件,染料敏化太阳能电池,染料溶液和化合物
- Patent Title: Metal complex dye, photoelectric conversion element, dye-sensitized solar cell, dye solution, and compound
- Patent Title (中): 金属络合染料,光电转换元件,染料敏化太阳能电池,染料溶液和化合物
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Application No.: US14301796Application Date: 2014-06-11
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Publication No.: US09564274B2Publication Date: 2017-02-07
- Inventor: Yukio Tani , Katsumi Kobayashi , Kimiatsu Nomura
- Applicant: FUJIFILM Corporation
- Applicant Address: JP Tokyo
- Assignee: FUJIFILM Corporation
- Current Assignee: FUJIFILM Corporation
- Current Assignee Address: JP Tokyo
- Agency: Sughrue Mion, PLLC
- Priority: JP2011-275129 20111215; JP2012-078148 20120329; JP2012-232400 20121019
- Main IPC: H01G9/20
- IPC: H01G9/20 ; C07D213/79 ; C07D401/04 ; C07D409/14 ; C09B57/10

Abstract:
A photoelectric conversion element, having: an electrically-conductive support; a photoconductor layer having a semiconductor fine-particle layer adsorbed a dye; a charge transfer layer containing an electrolyte; and a counter electrode; which are provided on one side of the support in this order, in which the dye has at least one terdentate ligand having at least one acidic group; at least one ligand coordinating to a metal atom M has an sp2 carbon atom; a cyclic group binds to the sp2 carbon atom; a specific substituent R is substituted at an atom of α- or β-position to the atom of the cyclic group directly binding to the sp2 carbon atom; and with the metal atom M, an atom G1 of the α- or β-position, and an atom G2 of the substituent R, an angle θ (∠MG1G2) is 150° or less.
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