Invention Grant
- Patent Title: Method for preparing diamino-dicyclohexyl methane
- Patent Title (中): 二氨基二环己基甲烷的制备方法
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Application No.: US14761890Application Date: 2013-11-22
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Publication No.: US09580380B2Publication Date: 2017-02-28
- Inventor: Xin Li , Hao Chen , Congying Zhang , Shan Gao , Zhenguo Liu , Weijia Wang , Lei Tang , Zhipeng Liu , Yuan Li , Qingmei Jiang , Jinhong Song , Weiqi Hua , Hao Ding
- Applicant: WANHUA CHEMICAL GROUP CO., LTD. , WANHUA CHEMICAL (NINGBO) CO., LTD.
- Applicant Address: CN Ningbo, Zhejiang
- Assignee: Wanhua Chemical Group Co., Ltd.
- Current Assignee: Wanhua Chemical Group Co., Ltd.
- Current Assignee Address: CN Ningbo, Zhejiang
- Agency: Buchanan Ingersoll & Rooney
- Priority: CN201310190370 20130522
- International Application: PCT/CN2013/087661 WO 20131122
- International Announcement: WO2014/187094 WO 20141127
- Main IPC: C07C209/72
- IPC: C07C209/72 ; B01J38/08 ; B01J23/96

Abstract:
Disclosed is a method for preparing diamino-dicyclohexyl methane (H12MDA) by hydrogenation of diamino-diphenyl methane (MDA). In the process, 4,4′-MDA used as the starting material is firstly hydrogenated to prepare 4,4′-H12MDA. When the activity of the catalyst is reduced, the feed is switched from 4,4′-MDA to the mixture of 2,4′-MDA and 4,4′-MDA, and then when the conversion is stabilized, the feed is switched to 4,4′-MDA again. The deactivated catalyst is activated on line by switching the feed to the mixture of 2,4′-MDA and 4,4′-MDA. 4,4′-H12MDA having the trans-trans isomer content of 16˜24 wt % is produced, and the mixture of 2,4′-H12MDA and 4,4′-H12MDA is also produced, wherein the content of 2,4′-H12MDA in the mixture is 4˜15 wt %.
Public/Granted literature
- US20160068472A1 METHOD FOR PREPARING DIAMINO-DICYCLOHEXYL METHANE Public/Granted day:2016-03-10
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