A method using Long Wave Infrared Imaging Polarimetry for improved mapping and perception of a roadway or path and for perceiving or detecting obstacles comprises recording raw image data using a polarimeter to obtain polarized images of the roadway or area. The images are then corrected for non-uniformity, optical distortion, and registration. IR and polarization data products are computed, and the resultant data products are converted to a multi-dimensional data set for exploitation. Contrast enhancement algorithms are applied to the multi-dimensional imagery to form enhanced object images. The enhanced object images may then be displayed to a user, and/or an annunciator may announce the presence of an object. Further, the vehicle may take evasive action based upon the presence of an object in the roadway.