Invention Grant
- Patent Title: Process for preparing acrylic acid from methanol and acetic acid
- Patent Title (中): 从甲醇和乙酸制备丙烯酸的方法
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Application No.: US14794955Application Date: 2015-07-09
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Publication No.: US09593065B2Publication Date: 2017-03-14
- Inventor: Lukas Schulz , Nicolai Tonio Woerz , Tim Blaschke , Marco Hartmann , Frank Huetten
- Applicant: BASF SE
- Applicant Address: DE Ludwigshafen
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE Ludwigshafen
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P.
- Priority: DE102014011476 20140731
- Main IPC: C07C51/347
- IPC: C07C51/347 ; B01J23/50 ; B01J27/198 ; C07C57/04 ; C07C45/38 ; C07C51/353 ; C07C45/32 ; C07C45/78

Abstract:
A process for preparing acrylic acid from methanol and acetic acid, comprising (i) contacting a gaseous stream S0 comprising methanol, oxygen and inert gas with an oxidation catalyst to obtain a gaseous stream S1 comprising formaldehyde and inert gas; (ii) removing at least a portion of the inert gas present in S1 from at least a portion of the formaldehyde present in S1 by absorbing this formaldehyde in an absorbent to obtain a gaseous stream S2 comprising the portion of the inert gas removed, and to obtain a stream S3 comprising absorbent and absorbate comprising formaldehyde; (iii) optionally removing a portion or the entirety of the absorbent present in stream S3, such that a stream S3a remains from stream S3, and producing a stream S4 from at least stream S3 or stream S3a and a stream S5 comprising acetic acid; and (iv) contacting stream S4 in gaseous form with an aldol condensation catalyst to obtain a gaseous stream S6 comprising acrylic acid.
Public/Granted literature
- US20160031789A1 PROCESS FOR PREPARING ACRYLIC ACID FROM METHANOL AND ACETIC ACID Public/Granted day:2016-02-04
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