- 专利标题: Method for producing polythiol compound, polymerizable composition for optical material, and uses thereof
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申请号: US14871563申请日: 2015-09-30
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公开(公告)号: US09637584B2公开(公告)日: 2017-05-02
- 发明人: Masaru Kawaguchi , Takeshi Nishimura
- 申请人: MITSUI CHEMICALS., INC.
- 申请人地址: JP Tokyo
- 专利权人: MITSUI CHEMICALS, INC.
- 当前专利权人: MITSUI CHEMICALS, INC.
- 当前专利权人地址: JP Tokyo
- 代理机构: Buchanan, Ingersoll & Rooney PC
- 优先权: JP2012-179896 20120814
- 主分类号: C08G18/38
- IPC分类号: C08G18/38 ; C07C319/20 ; C07C319/14 ; C07C335/32 ; C08G18/76 ; G02B1/04 ; C07C319/08 ; C07C381/00
摘要:
Provided is a method for producing a molded product comprising a step for preparing a polymerizable composition for optical materials and a step for curing the polymerizable composition for optical materials to produce the molded product. The step for preparing the polymerizable composition for optical materials comprises a step for preparing a defined polythiol compound and a step for preparing the polymerizable composition for optical materials from the polythiol compound. The step for preparing the defined polythiol compound comprises reacting 2-mercaptoethanol with a defined epihalohydrin compound at a temperature of 10° C. to 50° C. to obtain a defined polyalcohol compound, reacting the polyalcohol compound with thiourea in the presence of hydrogen chloride to obtain an isothiuronium salt, hydrolyzing the isothiuronium salt to obtain the polythiol compound, adding hydrochloric acid at a defined concentration to a solution of the polythiol compound, and washing the solution to purify the polythiol compound.
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