发明授权
- 专利标题: Continuous low-temperature process to produce trans-1-chloro-3,3,3-trifluoropropene
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申请号: US14195893申请日: 2014-03-04
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公开(公告)号: US09643903B2公开(公告)日: 2017-05-09
- 发明人: Konstantin A. Pokrovski , Daniel C. Merkel , Hsueh Sung Tung
- 申请人: Honeywell International Inc.
- 申请人地址: US NJ Morris Plains
- 专利权人: Honeywell International Inc.
- 当前专利权人: Honeywell International Inc.
- 当前专利权人地址: US NJ Morris Plains
- 代理商 Bruce O. Bradford
- 主分类号: C07C17/20
- IPC分类号: C07C17/20 ; B01D3/00 ; C01B7/07 ; C07C17/25 ; C07C17/358 ; C07C17/383 ; C07C21/18
摘要:
Disclosed is process for the production of (E) 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd(E)) by conducting a continuous reaction without the use of a catalyst. Also disclosed is an integrated system for producing hydrofluoro olefins, particularly 1233zd(E). The manufacturing process includes six major unit operations: (1) a fluorination reaction of HCC-240fa (in continuous or semi-batch mode) using HF with simultaneous removal of by-product HCl and the product 1233zd(E); (2) recycle of unreacted HCC-240fa and HF together with under-fluorinated by-products back to (1); (3) separation and purification of by-product HCl; (4) separation of excess HF back to (1); (5) purification of final product, 1233zd(E); and (6) isomerization of by-product 1233zd(Z) to 1233zd(E) to maximize the process yield.
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