Invention Grant
- Patent Title: Benzene-based diphosphine ligands for alkoxycarbonylation
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Application No.: US15213441Application Date: 2016-07-19
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Publication No.: US09725398B2Publication Date: 2017-08-08
- Inventor: Kaiwu Dong , Helfried Neumann , Ralf Jackstell , Matthias Beller , Robert Franke , Dieter Hess , Katrin Marie Dyballa , Dirk Fridag , Frank Geilen
- Applicant: EVONIK DEGUSSA GMBH
- Applicant Address: DE Essen
- Assignee: EVONIK DEGUSSA GMBH
- Current Assignee: EVONIK DEGUSSA GMBH
- Current Assignee Address: DE Essen
- Agency: Smith, Gambrell & Russell, LLP
- Priority: DE102015213918 20150723
- Main IPC: C07F9/28
- IPC: C07F9/28 ; B01J31/18 ; C07F15/00 ; C07C67/38 ; C07F9/58 ; C07F9/6506 ; B01J31/24 ; B01J31/22 ; C07F9/572 ; C07F9/655 ; C07F9/6553 ; C07F17/02

Abstract:
The invention relates to compounds of formula (I) where m and n are each independently 0 or 1; R1, R2, R3, R4 are each independently selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —(C6-C20)-aryl, —(C3-C20)-heteroaryl; at least one of the R1, R2, R3, R4 radicals is a —(C3-C20)-heteroaryl radical; and R1, R2, R3, R4, if they are —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —(C6-C20)-aryl or —(C3-C20)-heteroaryl, may each independently be substituted by one or more substituents selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —O—(C1-C12)-alkyl, —O—(C1-C12)-alkyl-(C6-C20)-aryl, —O—(C3-C12)-cycloalkyl, —S—(C1-C12)-alkyl, —S—(C3-C12)-cycloalkyl, —COO—(C1-C12)-alkyl, —COO—(C3-C12)-cycloalkyl, —CONH—(C1-C12)-alkyl, —CONH—(C3-C12)-cycloalkyl, —CO—(C1-C12)-alkyl, —CO—(C3-C12)-cycloalkyl, —N—[(C1-C12)-alkyl]2, —(C6-C20)-aryl, —(C6-C20)-aryl-(C1-C12)-alkyl, —(C6-C20)-aryl-O—(C1-C12)-alkyl, —(C3-C20)-heteroaryl, —(C3-C20)-heteroaryl-(C1-C12)-alkyl, —(C3-C20)-heteroaryl-O—(C1-C12)-alkyl, —COOH, —OH, —SO3H, —NH2, halogen; and to the use thereof as ligands in alkoxycarbonylation.
Public/Granted literature
- US20170022137A1 BENZENE-BASED DIPHOSPHINE LIGANDS FOR ALKOXYCARBONYLATION Public/Granted day:2017-01-26
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