This ultra-low-loss optical fiber comprises a core having a higher relative refractive index difference than silica and a cladding having a lower relative refractive index difference than silica. The relative refractive index difference of the core with respect to the refractive index of silica is 0.0030 to 0.0055, for example, and the relative refractive index difference of the cladding with respect to the refractive index of silica is −0.0020 to −0.0003. The ultra-low-loss optical fiber has the loss characteristic of simultaneously having optical losses of at most 0.324 dB/km at a wavelength of 1310 nm, at most 0.320 dB/km at a wavelength of 1383 nm, at most 0.184 dB/km at a wavelength of 1550 nm, and at most 0.20 dB/km at a wavelength of 1625 nm. The ultra-low-loss optical fiber is supercooled when the surface temperature of the optical fiber has a temperature range in a glass transition section during drawing.