Technologies are generally described to communicatively couple an optical fiber to an optical element using a polymer layer. An optical fiber may be coupled to an optical element, such as an optical waveguide or another optical fiber, using a layer of rewritable photorefractive polymer positioned between the optical fiber and the optical element. Light from a light source may be applied to the optical fiber to initiate a transient photorefractive effect in the polymer layer facilitating corrections of misalignment. A path of high refractive index may be formed in the polymer layer, where the path of high refractive index communicatively couples the optical fiber to the optical element reducing alignment concerns and increasing alignment tolerances of optical elements. In some examples, the path of high refractive index may be re-established by rewriting the polymer layer through another application of light from the light source if the communicative coupling is disrupted.