An apparatus for recovering refrigerant from an air conditioning system includes an evaporator arranged to receive the refrigerant from the air conditioning system and to separate it from impurities present in it, obtaining purified refrigerant, a compressor for circulating the purified refrigerant, a condenser, and a storage container arranged to contain the condensed refrigerant. The storage container defines a storage chamber arranged to contain a liquid phase of the refrigerant and a gaseous phase including a vapor component of the refrigerant and an air component. The apparatus also includes a measuring means configured to measure operating parameters of the refrigerant present in the storage chamber, purge device arranged at a purge opening configured to purge the gaseous phase present in the storage chamber responsive to the operating parameters, and at least one first separation chamber connected to the storage container.