Microspheres comprising a plurality of hollow microspheres, each of the plurality of hollow microspheres comprising a plurality of glass walls, and a plurality of hollow spaces, wherein the plurality of glass walls enclosing at least one of the plurality of hollow spaces, wherein the plurality of glass walls comprising a second glass, wherein the second glass comprising a processed first glass melt, wherein the processed first glass melt comprising a melt of a batch and a plurality of redox active group components capable of providing at least one of a plurality of redox reactions and a plurality of events in the second glass.