There is provided herein a composition which contains hydride-functionalized siloxane or silane, a hydroxyl-containing compound that does not contain silicon, and a catalytically-effective amount of super acid or super base catalyst selected from the group consisting of a triaza-containing compound which contains only carbon, nitrogen and hydrogen atoms, an atrane compound, a linear or branched compound containing a sulfonyl group and a fluoro group, and combinations thereof. There is also provided a process of making such a composition.