Silyl terminated prepolymers, method for making them and adhesive compositions made therefrom
Abstract:
An improved silane modified polymer useful in adhesive compositions is made from a silane precursor material made by a process comprising reacting an organic compound having a backbone that is terminated by an amino group having at least one active amino hydrogen and a hydrolysable silane, wherein the backbone is comprised of at least one secondary amino group having one active amino hydrogen and a Michael addition acceptor compound, wherein the Michael addition compound fails to have a group reactive with an isocyanate group to form the silane precursor compound. The silane precursor compound is reacted with an isocyanate terminated polyurethane prepolymer to form a silane modified prepolymer. The silane modified prepolymer may then be cured with moisture and may be employed in an adhesive composition containing other components such as a plasticizer, catalyst and filler.
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