- 专利标题: Method for preparing a hydrogel comprising silico-metallic mineral particles and hydrogel
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申请号: US14367702申请日: 2012-12-19
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公开(公告)号: US09968924B2公开(公告)日: 2018-05-15
- 发明人: Christophe Le Roux , Francois Martin , Pierre Micoud , Angela Dumas
- 申请人: Christophe Le Roux , Francois Martin , Pierre Micoud , Angela Dumas
- 申请人地址: FR Paris FR Toulouse
- 专利权人: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.),UNIVERSITE PAUL SABATIER TOULOUSE III
- 当前专利权人: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.),UNIVERSITE PAUL SABATIER TOULOUSE III
- 当前专利权人地址: FR Paris FR Toulouse
- 代理机构: Young & Thompson
- 优先权: FR1104027 20111222
- 国际申请: PCT/FR2012/052994 WO 20121219
- 国际公布: WO2013/093339 WO 20130627
- 主分类号: B01J13/00
- IPC分类号: B01J13/00 ; B01J37/03 ; C01B33/152 ; C01B33/38 ; C01B33/158 ; B01J21/06 ; B01J27/10 ; B01J31/02 ; B01J35/00
摘要:
A method for preparing a novel hydrogel including silico-metallic mineral particles of the formula (Six(Si-A)1−x)4M3O11.n′H2O, in which: x is a real number in the range [0.75; 1], A denotes a group selected from methyl and hydrocarbon groups including at least one heteroatom, and M is a metal selected from the group consisting of magnesium, cobalt, zinc, copper, manganese, iron, nickel and chromium, wherein a coprecipitation reaction is carried out in an aqueous medium between: at least one metal salt of the metal M, sodium metasilicate, Na2OSiO2, and at least one water-soluble oxysilane of formula (I): in which R1, R2 and R3 are selected from hydrogen and linear alkyl groups including 1 to 3 carbon atoms.
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