- 专利标题: Modular supramolecular approach for co-crystallization of donors and acceptors into ordered networks
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申请号: US15252852申请日: 2016-08-31
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公开(公告)号: US09997272B2公开(公告)日: 2018-06-12
- 发明人: Samuel I. Stupp , J. Fraser Stoddart , Alexander K. Shveyd , Alok S. Tayi , Chi-Hau Sue , Ashwin Narayanan
- 申请人: Northwestern University
- 申请人地址: US IL Evanston
- 专利权人: Northwestern University
- 当前专利权人: Northwestern University
- 当前专利权人地址: US IL Evanston
- 代理机构: Reinhart Boerner Van Deuren s.c.
- 主分类号: H01B1/00
- IPC分类号: H01B1/00 ; H01B1/12 ; C07D487/14 ; F21V9/00 ; G02B5/02 ; G02C7/10 ; G02F1/361 ; G03B11/00
摘要:
Organic charge-transfer (CT) co-crystals in a mixed stack system are disclosed, wherein a donor molecule (D) and an acceptor molecule (A) occupy alternating positions (DADADA) along the CT axis. A platform is provided which amplifies the molecular recognition of donors and acceptors and produces co-crystals at ambient conditions, wherein the platform comprises (i) a molecular design of the first constituent (α-complement), (ii) a molecular design of the second compound (β-complement), and (iii) a solvent system that promotes co-crystallization.
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