发明授权
UST970008I4 Removal and recovery of sulfur oxides from gas streams with melamine
失效
用三聚氰胺从气流中除去和回收硫氧化物
- 专利标题: Removal and recovery of sulfur oxides from gas streams with melamine
- 专利标题(中): 用三聚氰胺从气流中除去和回收硫氧化物
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申请号: US794269申请日: 1977-05-05
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公开(公告)号: UST970008I4公开(公告)日: 1978-05-02
- 发明人: John J. Kohler , Joe Gautney , Yong K. Kim , John F. McCullough
- 申请人: John J. Kohler , Joe Gautney , Yong K. Kim , John F. McCullough
- 专利权人: Tennessee Valley Authority
- 当前专利权人: Tennessee Valley Authority
- 主分类号: B01D53/50
- IPC分类号: B01D53/50
摘要:
a process for the removal and recovery of sulfur oxides from gas streams by contacting the gas stream with an aqueous suspension of melamine containing an oxidation inhibitor such as para-phenylenediamine whereupon a mixture of solid, hydrated melamine sulfites and solid, hydrated melamine sulfate is formed. The solids are then separated from the reaction product and the clarified liquid recycled. The solids are then heated to temperatures up to 200.degree. C to decompose the hydrated melamine sulfites into free melamine, gaseous water, and sulfur dioxide, and the gaseous water and sulfur dioxide withdrawn as product. The hot solids are cooled and split into two portions. One portion is recycled and the other portion is treated with an aqueous inorganic base stronger than melamine such as ammonia or potassium hydroxide to decompose the contained melamine sulfate into free melamine and a basic sulfate salt solution. The basic sulfate salt solution is separated from the melamine and withdrawn as product and the melamine is recycled to the process.
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