Invention Application
- Patent Title: SOLID ELASTOMERIC BLOCK COPOLYMERS
- Patent Title (中): 固体弹性体嵌段共聚物
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Application No.: PCT/US9301414Application Date: 1993-02-17
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Publication No.: WO9316121A3Publication Date: 1993-09-16
- Inventor: COOLBAUGH THOMAS SMITH , LOVELESS FREDERICK CHARLES , MATTHEWS DEMETREOS NESTOR
- Applicant: MOBIL OIL CORP
- Assignee: MOBIL OIL CORP
- Current Assignee: MOBIL OIL CORP
- Priority: US83657792 1992-02-18
- Main IPC: C08F8/00
- IPC: C08F8/00 ; C08F8/04 ; C08F8/44 ; C08F8/46 ; C08F236/04 ; C08F297/02 ; C08F297/04 ; C08L51/00 ; C08L53/00 ; C08L53/02
Abstract:
There are disclosed novel, solid, elastomeric block copolymers with improved resistance to cold flow wherein either 1) the terminal blocks are each a polymer (I polymer) of at least one conjugated diene (I), e.g., isoprene, which contains at least five carbon atoms with at least one of each pair of double-bonded carbon atoms in the polymerized diene I units being additionally single-bonded to two carbon atoms; at least one middle or interior block is a hydrogenated polybutadiene (B polymer); and at least one middle or interior block is an essentially straight chain polyethylene (E polymer) resulting from the hydrogenation of a polybutadiene composed of at least 80 % of 1,4- units; or 2) the terminal blocks are random copolymers resulting from the hydrogenation of a copolymer of at least one diene I as previously defined and hydrogenated butadiene, and at least one middle or interior block is a straight chain polyethylene (E polymer) as previously defined. The hydrogenated butadiene units in the B polymer or random IB polymer blocks are composed of no more than about 65 % of 1,4- units and at least about 35 % of 1,2- units. The foregoing block copolymers may be prepared by selectively hydrogenating substantially all the butadiene units of a precursor block, copolymer wherein the precursor blocks of the straight chain polyethylene block units are polybutadiene blocks in which at least about 80 % of the butadiene units are 1,4- units. A sufficient number of I units in the I polymer blocks or random IB copolymer blocks retain their unsaturation on selective hydrogenation to enable the vulcanization of the block copolymer.
Information query