Invention Application
WO1996015189A1 FILMS FROM AQUEOUS DISPERSIONS OF BLOCK COPOLYMERS HAVING HYDROGENATED CONJUGATED DIENE BLOCK 审中-公开
具有加氢混合二烯嵌段的嵌段共聚物的水分散体膜

FILMS FROM AQUEOUS DISPERSIONS OF BLOCK COPOLYMERS HAVING HYDROGENATED CONJUGATED DIENE BLOCK
Abstract:
Aqueous dispersions, and films prepared therefrom, comprising an organic phase of block copolymers and optional extenders wherein the block copolymers corresponds to the formula: A-B-Xm-(B-A)n wherein each A is a polymer block of a monovinylidene aromatic monomer and conjugated dienes, each B is a polymer block of one or more conjugated dienes and, optionally, one or more monovinylidene aromatic monomers, X is the remnant of a multifunctional coupling agent, m is 0 or 1, and n is an integer from 1 to 5. Each A polymer block has a weight average molecular weight from 4,000 to 15,000 Daltons. Each B polymer block has a weight average molecular weight from 20,000 to 200,000 Daltons. The total monovinylidene monomer content is from 6 to 30 percent by weight of the organic phase. The effective phase volume of the A polymer block in the organic phase is from 8 to 20 percent. Thin elastomeric articles prepared from the emulsions have improved tensile strength properties. Also claimed is a process for the preparation of such films.
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