Invention Application
WO2005005353A8 HYDRODTREATING OF FISCHER-TROPSCH DERIVED FEEDS PRIOR TO OLIGOMERIZATION USING AN IONIC LIQUID CATALYST
审中-公开
使用离子液体催化剂进行过渡化过程中FISCHER-TROPSCH衍生的进料的加氢
- Patent Title: HYDRODTREATING OF FISCHER-TROPSCH DERIVED FEEDS PRIOR TO OLIGOMERIZATION USING AN IONIC LIQUID CATALYST
- Patent Title (中): 使用离子液体催化剂进行过渡化过程中FISCHER-TROPSCH衍生的进料的加氢
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Application No.: PCT/US2004017991Application Date: 2004-06-03
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Publication No.: WO2005005353A8Publication Date: 2006-08-03
- Inventor: JOHNSON DAVID R , HARRIS THOMAS V , DRIVER MICHAEL S
- Applicant: CHEVRON USA INC , JOHNSON DAVID R , HARRIS THOMAS V , DRIVER MICHAEL S
- Assignee: CHEVRON USA INC,JOHNSON DAVID R,HARRIS THOMAS V,DRIVER MICHAEL S
- Current Assignee: CHEVRON USA INC,JOHNSON DAVID R,HARRIS THOMAS V,DRIVER MICHAEL S
- Priority: US61159403 2003-06-30
- Main IPC: C07C2/00
- IPC: C07C2/00 ; C07C2/04 ; C10G2/00 ; C10G9/00 ; C10G45/02 ; C10G45/58 ; C10G50/02 ; C10G57/02 ; C10G69/06 ; C10G69/12
Abstract:
A process for oligomerizing a Fischer-Tropsch derived feed containing oxygenates which comprises (a) reducing significantly the oxygenates present in the Fischer-Tropsch derived feed by contacting said feed with a hydrotreating catalyst under hydrotreating conditions in a hydrotreating zone (8) and recovering from the hydrotreating zone a Fischer-Tropsch derived hydrotreated feed (10) which contains a significantly reduced amount of oxygenates as compared to the Fischer-Tropsch derived feed and also a significant amount of paraffins; (b) pyrolyzing the Fischer-Tropsch derived hydrotreated feed in a thermal cracking zone (12) under thermal cracking conditions pre-selected to crack the paraffin molecules to form olefins and collecting an olefin-enriched Fischer-Tropsch feed (14) from the thermal cracking zone (14); (c) contacting the olefin-enriched Fischer-Tropsch feed with a Lewis acid ionic liquid catalyst in an oligomerization zone (16) under oligomerization reaction conditions; and (d) recovering from the oligomerization zone a Fischer-Tropsch derived product (18) having molecules characterized by a higher average molecular weight and increased branching as compared to the Fischer-Tropsch derived feed.
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