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发明申请
WO2006018161A3 IMMOBILIZABLE RUTHENIUM(II)-CATALYSTS WITH A SUBSTITUTED CENTRAL ATOM, METHOD FOR THE PRODUCTION AND USE THEREOF 审中-公开
在中环原子取代，可固定钌（II）催化剂，方法使用和

IMMOBILIZABLE RUTHENIUM(II)-CATALYSTS WITH A SUBSTITUTED CENTRAL ATOM, METHOD FOR THE PRODUCTION AND USE THEREOF
摘要：
The invention relates to immobilizable ruthenium(II)-catalysts having general formulae (I) and (II), containing an SiR' n (OR') 3-n structural group on at least one of the two anions. The invention also relates to a method for the production and use of compounds in a method for the production of ruthenium (II)-catalysts having general formulae (I) and (II) immobilized on inorganic oxide carriers. The invention further relates to the use of compounds having general formulae (I), (la), (II) and (IIa) as catalysts in organic and metalorganic synthesis. Said compounds can be used as catalysts in C-C coupling reactions, hydrogenations, isomerizations, silylations and hydroformylations. They can be used in particular as catalysts in olefin metathetical reactions such as cross metathesis (CM), ring closure metathesis (RCM), ring opening metathesis (ROM), ring opening metathesis-polymerization (ROMP), acyclic diene metathesis-polymerization (ADMET) and En-In metathesis or in a combination of various metathetical reactions.
摘要（中）：

本发明涉及一种可固定钌（II）通式（I）和（II）的SIR '名词（OR'） 3-n的组轴承在催化剂 两个阴离子中的至少一个。 本发明还涉及用于它们的制备方法和在方法中的用途的化合物的用于生产无机氧化物载体固定化的钌（II）通式（Ia）和催化剂（IIa）中。 本发明还提供了通式（I），（IA），（II）和化合物（IIA），如有机和有机金属合成催化剂。 它们可以被用来作为在C-C偶联反应，氢化，异构化，Silylations和加氢甲酰化催化剂。 特别是，它们用作在烯烃复分解反应，如交叉复分解（CM），闭环复分解（RCM），开环复分解（ROM），开环易位聚合（ROMP），无环二烯烃易位聚合（ADMET），催化剂和烯炔结合复分解或不同类型 复分解反应。

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