Invention Application
WO2010056299A1 INTEGRATED PROCESS FOR THE PRODUCTION OF VINYL ACETATE FROM ACETIC ACID VIA ETHYLENE
审中-公开
通过乙烯从乙酸生产乙酸乙烯酯的综合方法
- Patent Title: INTEGRATED PROCESS FOR THE PRODUCTION OF VINYL ACETATE FROM ACETIC ACID VIA ETHYLENE
- Patent Title (中): 通过乙烯从乙酸生产乙酸乙烯酯的综合方法
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Application No.: PCT/US2009/006016Application Date: 2009-11-06
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Publication No.: WO2010056299A1Publication Date: 2010-05-20
- Inventor: JOHNSTON, Victor, J. , CHEN, Laiyuan , ZINK, James, H. , CHAPMAN, Josefina, T. , KIMMICH, Barbara, F. , REPMAN, Deborah, R.
- Applicant: CELANESE INTERNATIONAL CORPORATION , JOHNSTON, Victor, J. , CHEN, Laiyuan , ZINK, James, H. , CHAPMAN, Josefina, T. , KIMMICH, Barbara, F. , REPMAN, Deborah, R.
- Applicant Address: 1601 West LBJ Freeway Dallas, TX 75234-6034 US
- Assignee: CELANESE INTERNATIONAL CORPORATION,JOHNSTON, Victor, J.,CHEN, Laiyuan,ZINK, James, H.,CHAPMAN, Josefina, T.,KIMMICH, Barbara, F.,REPMAN, Deborah, R.
- Current Assignee: CELANESE INTERNATIONAL CORPORATION,JOHNSTON, Victor, J.,CHEN, Laiyuan,ZINK, James, H.,CHAPMAN, Josefina, T.,KIMMICH, Barbara, F.,REPMAN, Deborah, R.
- Current Assignee Address: 1601 West LBJ Freeway Dallas, TX 75234-6034 US
- Agency: FERRELL, Michael, W.
- Priority: US12/291,949 20081114
- Main IPC: C07C67/05
- IPC: C07C67/05
Abstract:
This invention provides an integrated two stage economical process for the production of vinyl acetate monomer (VAM) from acetic acid in the vapor phase. First, acetic acid is selectively hydrogenated over a hydrogenating catalyst composition to form ethylene either in a single reactor zone or in a dual reactor zone wherein the intermediate hydrogenated products are either dehydrated and/or cracked to form ethylene. In a subsequent second stage so formed ethylene is reacted with molecular oxygen and acetic acid over a suitable catalyst to form VAM. In an embodiment of this invention reaction of acetic acid and hydrogen over a hydrogenation catalyst and subsequent reaction over a dehydration catalyst selectively produces ethylene, which is further mixed with acetic acid and molecular oxygen and reacted over a supported palladium/gold/potassium catalyst.
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