Invention Application
WO2014079971A1 HIGH PERFORMANCE ZIEGLER-NATTA CATALYST SYSTEMS, PROCESS FOR PRODUCING SUCH SUPPORTED CATALYSTS AND USE THEREOF
审中-公开
高性能ZIEGLER-NATTA催化剂体系,生产这种支持催化剂的方法及其用途
- Patent Title: HIGH PERFORMANCE ZIEGLER-NATTA CATALYST SYSTEMS, PROCESS FOR PRODUCING SUCH SUPPORTED CATALYSTS AND USE THEREOF
- Patent Title (中): 高性能ZIEGLER-NATTA催化剂体系,生产这种支持催化剂的方法及其用途
-
Application No.: PCT/EP2013/074468Application Date: 2013-11-22
-
Publication No.: WO2014079971A1Publication Date: 2014-05-30
- Inventor: DENKWITZ, Yvonne , SCHUSTER, Oliver , WINTER, Andreas
- Applicant: LUMMUS NOVOLEN TECHNOLOGY GMBH
- Applicant Address: Gottlieb Daimlerstr.8 68165 Mannheim DE
- Assignee: LUMMUS NOVOLEN TECHNOLOGY GMBH
- Current Assignee: LUMMUS NOVOLEN TECHNOLOGY GMBH
- Current Assignee Address: Gottlieb Daimlerstr.8 68165 Mannheim DE
- Agency: GIOVANNINI, Francesca et al.
- Priority: US61/729,907 20121126
- Main IPC: C08F10/00
- IPC: C08F10/00 ; C08F4/651 ; C08F4/654
Abstract:
A method for making a solid catalyst component for use in a Ziegler-Natta catalyst includes combining in a hydrocarbon solvent a porous particulate support with a hydrocarbon soluble organomagnesium compound to form a suspension. The organomagnesium compound is halogenated followed by addition of an alcohol and the mixture is then reacted with a titanium compound followed by a reaction with at least one diether compound to form the solid catalyst component. Afterwards the reaction product is extracted with a mixture of a titanium compound and a hydrocarbon solvent. The solid catalyst component recovered is combined with an aluminum cocatalyst to form a Ziegler- Natta catalyst system for the polymerization of olefins. In particular, the catalyst system including a diether internal electron donor may have an activity and hydrogen response suitable for the production of propylene polymers having a molecular weight distribution (PI(GPC)) in the range from about 5.75 to about 9.
Information query