发明申请
WO2016008035A1 HIGH PRODUCTIVITY KOLBE REACTION PROCESS FOR TRANSFORMATION OF FATTY ACIDS DERIVED FROM PLANT OIL AND ANIMAL FAT 审中-公开
用于转化从植物油和动物脂肪中提取的脂肪酸的高生产力KOLBE反应过程

HIGH PRODUCTIVITY KOLBE REACTION PROCESS FOR TRANSFORMATION OF FATTY ACIDS DERIVED FROM PLANT OIL AND ANIMAL FAT
摘要:
Oils from plants and animal fats are hydrolyzed to fatty acids for a Kolbe reaction. The invention relates to a high productivity Kolbe reaction process for electrochemically decarboxylating C4-C28 fatty acids using small amounts of acetic acid to lower anodic passivation voltage and synthesizing C6-C54 hydrocarbons. The C6-C54 undergo olefin metathesis and/or hydroisomerization reaction process to synthesize heavy fuel oil, diesel fuel, kerosene fuel, lubricant base oil, and linear alpha olefin products useful as precursors for polymers, detergents, and other fine chemicals.
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