发明申请
WO2016091681A1 POLYETHYLENE COMPOSITION AND PIPE COMPRISING SUCH COMPOSITION
审中-公开
聚乙烯组合物和包含这种组合物的管道
- 专利标题: POLYETHYLENE COMPOSITION AND PIPE COMPRISING SUCH COMPOSITION
- 专利标题(中): 聚乙烯组合物和包含这种组合物的管道
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申请号: PCT/EP2015/078359申请日: 2015-12-02
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公开(公告)号: WO2016091681A1公开(公告)日: 2016-06-16
- 发明人: HABIBI, Salaheldin , M A. , MOMAN, Akhlaq , AL-OTAIBI, Abdullah, Shamroukh
- 申请人: SABIC GLOBAL TECHNOLOGIES B.V.
- 申请人地址: Plasticslaan 1 4612 PX Bergen op Zoom NL
- 专利权人: SABIC GLOBAL TECHNOLOGIES B.V.
- 当前专利权人: SABIC GLOBAL TECHNOLOGIES B.V.
- 当前专利权人地址: Plasticslaan 1 4612 PX Bergen op Zoom NL
- 代理机构: SABIC INTELLECTUAL PROPERTY GROUP
- 优先权: EP14197549.0 20141212; US62/099,613 20150105
- 主分类号: F16L9/12
- IPC分类号: F16L9/12 ; C08L23/08 ; C08F210/16 ; C08F4/656 ; C08K3/04
摘要:
The invention relates to a pipe comprising polyethylene or a polyethylene composition comprising polyethylene and carbon black, wherein the polyethylene is produced in the presence of a solid catalyst component and a co-catalyst, wherein the solid catalyst component is prepared by a process comprising the steps of: (a) contacting a dehydrated support having hydroxyl groups with a magnesium compound having the general formula MgR 1 R 2 , wherein R 1 and R 2 are the same or different and are independently selected from the group comprising an alkyl group, alkenyl group, alkadienyl group, aryl group, alkaryl group, alkenylaryl group and alkadienylaryl group; (b) contacting the product obtained in step (a) with modifying compounds (A), (B) and (C), wherein: (A) is at least one compound selected from the group consisting of carboxylic acid, carboxylic acid ester, ketone, acyl halide, aldehyde and alcohol; (B) is a compound having the general formula R 11 f(R 12 O) g SiX h , wherein f, g and h are each integers from 0 to 4 and the sum of f, g and h is equal to 4 with a proviso that when h is equal to 4 then modifying compound (A) is not an alcohol, Si is a silicon atom, O is an oxygen atom, X is a halide atom and R 11 and R 12 are the same or different and are independently selected from the group comprising an alkyl group, alkenyl group, alkadienyl group, aryl group, alkaryl group, alkenylaryl group and alkadienylaryl group; (C) is a compound having the general formula (R 13 O) 4 M, wherein M is a titanium atom, a zirconium atom or a vanadium atom, O is an oxygen atom and R 13 is selected from the group comprising an alkyl group, alkenyl group, alkadienyl group, aryl group, alkaryl group, alkenylaryl group and alkadienylaryl group; and (c) contacting the product obtained in step (b) with a titanium halide compound having the general formula TiX 4 , wherein Ti is a titanium atom and X is a halide atom, whereby the polyethylene has a molecular weight Mz+1 of at least 720,000 g/mol and less than 2,500,000 g/mol.