A protective composite material that includes a first layer that includes at least one of a polychloroprene film or a poly (vinyl chloride) film; a second layer comprising a fabric substrate having at least one of m-aramid fibers and/or p-aramid fibers, disposed on the first layer; and a third layer comprising polychloroprene disposed adjacent to the second layer, wherein the second layer is disposed between the first layer and the third layer. A fourth barrier layer is optionally disposed on the third layer.