Invention Application
- Patent Title: OIL-IN-WATER EMULSIONS
- Patent Title (中): 水包油乳液
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Application No.: PCT/GB2016/053413Application Date: 2016-11-03
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Publication No.: WO2017077302A2Publication Date: 2017-05-11
- Inventor: CRAIGE, Simon , MILES, Jason Victor , SELSE, Dennis , KRIGSMAN, Joakim
- Applicant: QUADRISE INTERNATIONAL LTD , AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
- Applicant Address: 1st Floor, Gillingham House 38-44 Gillingham Street London SW1V 1HU GB
- Assignee: QUADRISE INTERNATIONAL LTD,AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
- Current Assignee: QUADRISE INTERNATIONAL LTD,AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
- Current Assignee Address: 1st Floor, Gillingham House 38-44 Gillingham Street London SW1V 1HU GB
- Agency: BROOKES BATCHELLOR LLP
- Priority: GB1519615.7 20151106; GB1609042.5 20160523
- Main IPC: C10L1/222
- IPC: C10L1/222 ; C10L1/32 ; B01F17/00 ; G01N33/28
Abstract:
The invention relates to an oil-in-water emulsion comprising an oil phase and an aqueous phase, and a primary surfactant, wherein the oil phase is dispersed in the aqueous phase, and wherein the oil-in-water emulsion has: an average droplet size distribution (D[4,3]) in the range of from 3 to 15 µm and less than 3wt% of the droplets have a particle size of greater than 125 µm;a viscosity of greater than 100 and up to 700 mPas at 50°C ±10% and 20 s -1 ±10%; and a static stability of less than 5% residue after centrifugation at 50°C ±10% and 2000g ±10% for 30 minutes ±10%. A process for preparing such an oil-in-water emulsion comprises preparing an aqueous phase comprising a primary surfactant, heating a hydrocarbon-containing oil-phase, and blending the hydrocarbon-containing oil and the aqueous phase under conditions sufficient to form an oil-in-water emulsion. The invention also relates to methods for determining the static and dynamic stability of oil-in-water emulsions. Static stability can be determined by a method comprising the steps of: providing an oil-in-water emulsion; centrifuging the oil-in-water emulsion under predetermined conditions for a predetermined period of time; determining the amount of residue deposited from the oil-in-water emulsion after the predetermined period of time; and determining the oil-in-water emulsion's static stability. A method for determining the dynamic stability of an oil-in-water emulsion comprises the steps of: providing an oil-in-water emulsion; analysing the oil-in-water emulsion at a first time; recirculating the oil-in-water emulsion in a recirculation loop; and analysing the oil-in- water emulsion at second time after recirculation has started; in which the oil-in-water emulsion's dynamic stability is determined based on the analysis at the first and second times.
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