SELECTIVE AREA DEPOSITION OF METAL LAYERS FROM HETERO-PENTADIENYL METAL COMPLEX PRECURSORS
Abstract:
Metal layers including a metal M are selectively deposited on metal surfaces via chemical vapor deposition or atomic layer deposition from a hetero-pentadienyl metal complex precursor of formula (I), wherein L is a ligand; n is 1, 2 or 3; X is NR 1 , S(O)(O), S(O)(R 1 )(R 1 ), S(R 1 )(R 1 ), P(O)(R 1 ), P(R 1 )(R 1 )(R 1 ) or O; each R independently is hydrogen or a straight or branched chain C 1 -C 6 alkyl; each R 1 independently is hydrogen or a straight or branched chain C 1 -C 6 alkyl; and M is a first row late transition metal or a platinum group metal.
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