PROCESS FOR THE PREPARATION OF MULTIMODAL HIGH DENSITY POLYETHYLENE
Abstract:
The invention provides a process for the preparation of a multimodal high density polyethylene (HDPE) having a melt flow rate (MFR 2 ) of 0.1 to 4.0 g/1O min, said process comprising: (i) polymerising ethylene in a first polymerisation stage in the presence of a Ziegler-Natta catalyst to prepare a first ethylene homopolymer having a MFR 2 from 10 to 500 g/1O min; (ii) polymerising ethylene in a second polymerisation stage in the presence of said catalyst and said first ethylene homopolymer to prepare an ethylene homopolymer mixture comprising said first ethylene homopolymer and a second ethylene homopolymer, said mixture having a MFR 2 from 50 to 1000 g/1O min; and (iii) polymerising ethylene and at least one alpha-olefin comonomer in a third polymerisation stage in the presence of said catalyst and said ethylene homopolymer mixture to prepare said multimodal HDPE.
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