An array of discrete nanofiber films that are physically separated from one another are described. Techniques for forming the nanofiber film array are also described. Techniques for forming these structures include placing a suspension of nanofibers and/or nanoparticles on a patterned substrate. A pressure differential is applied, drawing the solvent of the suspension through holes in a mask. The nanofibers collect on an impermeable layer on the mask in a pattern corresponding to the negative features (grooves, holes, trenches) of the mask as the solvent is flowed through the holes.