发明申请
- 专利标题: BUTADIENE NITRILE LATEX, LATEX COMPOSITION FOR DIP-MOLDING, AND DIP-MOLDED ARTICLE
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申请号: PCT/RU2022/050301申请日: 2022-09-23
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公开(公告)号: WO2023048601A1公开(公告)日: 2023-03-30
- 发明人: KORYSTINA, Ludmila Andreevna , BAGRYASHOV, Sergej Viktorovich
- 申请人: PUBLIC JOINT STOCK COMPANY "SIBUR HOLDING" (PJSC "SIBUR HOLDING")
- 申请人地址: Vostochnyj promyshlennyj rayon, kvartal 1, No. 6, stroenie 30
- 专利权人: PUBLIC JOINT STOCK COMPANY "SIBUR HOLDING" (PJSC "SIBUR HOLDING")
- 当前专利权人: PUBLIC JOINT STOCK COMPANY "SIBUR HOLDING" (PJSC "SIBUR HOLDING")
- 当前专利权人地址: Vostochnyj promyshlennyj rayon, kvartal 1, No. 6, stroenie 30
- 代理机构: VESELITSKIY, Maxim Borisovich et al.
- 优先权: RU2021128244 2021-09-27
- 主分类号: C08L9/04
- IPC分类号: C08L9/04 ; C08L9/10 ; C08F236/12 ; C08F236/14 ; C08J5/02 ; A61B42/10
摘要:
The present invention relates to carboxylated butadiene nitrile latex, used for manufacturing of the dip-molded articles, in particular for production of latex gloves for industrial and medical purpose. More particular, the present invention relates to a latex for the manufacture of the dip-molded articles, comprising structural units formed from at least one monomer which is conjugated diene, at least one ethylene unsaturated monomer comprising a nitrile group, and at least one monomer which is an unsaturated carboxylic acid, where the value of the solubility index (A), calculated by the formula А=100 * p *S /(Mn+Mw) is 0.5 to 22 wt%*nm*mol*g-1, where p is polymer solubility in methyl ethyl ketone (wt%), S - latex particle size (nm), Mn – number-average molecular weight of the tetrahydrofuran-soluble fraction of butadiene-nitrile latex (g/mol), Mw is weight average molecular weight of the tetrahydrofuran-soluble fraction of butadiene-nitrile latex (g/mol), with the polydispersity value of latex polymer Mw/Mn of 2.0 to 5.0. The present invention also relates to a dip-molding composition based on butadiene-nitrile latex, to a dip-molded article and to a glove, manufactured based on the latex composition according to the present invention.