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1.发明公开
公开(公告)号：EP4134383A1
公开(公告)日：2023-02-15
申请号：EP21796320.6
申请日：2021-04-26
申请人： China Petroleum & Chemical Corporation , BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
发明人： CUI, Nannan , GUO, Zifang , GOU, Qingqiang , LI, Bingyi , WANG, Ruen , LI, Yan , FU, Jie , YAN, Lixin , AN, Jingyan , KOU, Peng , XU, Shiyuan , ZHANG, Tongxuan
摘要： The present disclosure relates to olefin polymerization catalysts, and discloses a catalyst component for olefin polymerization or copolymerization and a preparation method therefor, and a catalyst and an application thereof. The catalyst component for olefin polymerization or copolymerization in the present disclosure comprises titanium element, magnesium element, an electron donor, an organic silicon polymer, and an inorganic oxide support, wherein the molecular composition of the organic silicon polymer is [R x SiO (4-x)/2 ] m , wherein R is selected from alkyl, aryl, vinyl or oxygen, x is 0 or more and 2 or less, and the value of m makes the number-average molecular weight of the organic silicon polymer be 1×10 3 -1×10 6 g/mol. The catalyst has the characteristics of high activity, good hydrogen-regulating copolymerization performance, high bulk density of resulting polymer powder, and a low content of fine powder in the polymer powder when applied to olefin polymerization, particularly to ethylene and α-olefin polymerization.
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2.发明公开COMPLEX SUPPORT SUITABLE FOR PROPYLENE POLYMERIZATION CATALYST, A CATALYST COMPONENT AND CATALYST CONTAINING THE SAME 有权KOMPLEXERTRÄGERFÜR丙烯醇聚合物，KATALYSATOMPONENTE UND KATALYSATOR DAMIT
公开(公告)号：EP1609805A1
公开(公告)日：2005-12-28
申请号：EP04711555.5
申请日：2004-02-17
申请人： China Petroleum & Chemical Corporation , Beijing Research Institute of Chemical Industry, China Petroleum &Chemical Corporation
发明人： CHEN, Wei , ZHANG, Tianyi , DU, Hongbin , XIA, Xianzhi , ZHANG, Tongxuan , YAN, Lixin , WANG, Yisen , WANG, Xinsheng , LI, Jiyu , GAO, Ping , YIN, Maoping , YU, Luqing , MA, Qingshan , WANG, Xiaodong
CPC分类号： C08F10/00 , C08F10/06 , C08F110/06 , C08F4/651 , C08F4/025 , C08F4/022 , C08F4/6543 , C08F2500/12 , C08F2500/04 , C08F4/6465
摘要： The present invention is to provide a composite carrier, which is spheric particles obtainable by contacting magnesium halide with one or more electron donor compounds to form a solution, then mixing the solution with silica material having an average particle size of less than 10 microns to form a mixture, and drying the mixture through spray drying process. The present invention is also to provide a catalyst component comprising said composite carrier. When the catalyst component is used together with a cocatalyst component in propylene polymerization, it exhibits higher polymerization activity and stereospecificity, and can be used to prepare high impact resistent ethylene-propylene copolymer having high ethylene content.
摘要翻译： 本发明提供一种复合载体，其是通过使卤化镁与一种或多种电子给体化合物接触以形成溶液而获得的球形颗粒，然后将该溶液与平均粒度小于10微米的二氧化硅材料混合以形成 混合物，并通过喷雾干燥过程干燥混合物。 本发明还提供包含所述复合载体的催化剂组分。 当催化剂组分与丙烯聚合中的助催化剂组分一起使用时，其表现出较高的聚合活性和立体定向性，并且可用于制备具有高乙烯含量的高抗冲击乙烯 - 丙烯共聚物。
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3.发明授权COMPLEX SUPPORT SUITABLE FOR PROPYLENE POLYMERIZATION CATALYST, A CATALYST COMPONENT AND CATALYST CONTAINING THE SAME 有权复合载体FOR PROPYLENPOLYMERISATIONSKATALYSATOR催化剂组分和催化剂，使得
公开(公告)号：EP1609805B1
公开(公告)日：2012-10-17
申请号：EP04711555.5
申请日：2004-02-17
申请人： China Petroleum & Chemical Corporation , Beijing Research Institute of Chemical Industry, China Petroleum &Chemical Corporation
发明人： CHEN, Wei , ZHANG, Tianyi , DU, Hongbin , XIA, Xianzhi , ZHANG, Tongxuan , YAN, Lixin , WANG, Yisen , WANG, Xinsheng , LI, Jiyu , GAO, Ping , YIN, Maoping , YU, Luqing , MA, Qingshan , WANG, Xiaodong
CPC分类号： C08F10/00 , C08F10/06 , C08F110/06 , C08F4/651 , C08F4/025 , C08F4/022 , C08F4/6543 , C08F2500/12 , C08F2500/04 , C08F4/6465
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