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1.发明授权VULCANIZABLE CHLORINATED ELASTOMER COMPOSITIONS WITH IMPROVED PROCESSING SAFETY AND CURE RATE 有权具有改进的安全，提高治愈率硫化氯化弹性体组合物
公开(公告)号：EP1861460B1
公开(公告)日：2010-09-29
申请号：EP06836033.8
申请日：2006-03-10
IPC分类号： C08K5/3432 , C08K5/3445 , C08L23/28 , C08K5/19 , C08K5/47
CPC分类号： C08K5/34 , C08K5/46 , C08L11/00 , C08L23/286 , C08L23/28
摘要： The instant invention is an improved cure system composition and a method for curing chlorinated elastomer compositions. The cure system composition includes a polymercapto crosslinking agent, an inorganic base, and a quaternary ammonium salt. The quaternary ammonium salt has a formula selected from the group consisting of wherein R1 is an alkyl or aryl group containing between 4 and 12 carbon atoms; wherein R2 and R3 are independently alkyl or aryl groups containing between 1 and 8 carbon atoms; wherein the total number of carbon atoms on R2 and R3 are between 3 and 9; wherein R4 and R5 are methyl groups, and R6 is an alkyl group containing between 2 and 8 carbon atoms; and wherein X is an anion. The method for curing a chlorinated elastomer, composition according to instant invention includes the following steps: (1) providing a chlorinated elastomer composition; (2) providing a cure system composition as described above; (3) contacting said chlorinated elastomer composition with said cure system composition; and (4) thereby curing said chlorinated elastomer composition.
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2.发明公开A CURE SYSTEM FOR HALOGENATED ELASTOMER COMPOSITIONS, A CURABLE HALOGENATED ELASTOMER COMPOSITION, AND A METHOD FOR CURING HALOGENATED ELASTROMER COMPOSITIONS 有权硫化体系卤化弹性体组合物可固化卤化弹性组合物和方法用于治疗卤化弹性体组合物
公开(公告)号：EP1960462A1
公开(公告)日：2008-08-27
申请号：EP07853513.5
申请日：2007-08-21
IPC分类号： C08K3/22 , C08K3/24 , C08K5/092 , C08K5/098 , C08K5/17 , C08K5/18 , C08K5/46 , C08K5/47 , C08K5/49 , C08K5/50 , C08K5/3415 , C08K5/3432 , C08K5/3445 , C08K5/36 , C08K5/09
CPC分类号： C08K5/0025 , C08K5/098 , C08K5/47 , C08L23/286 , C08L81/00 , C08L2312/00 , C08L11/00 , C08L2666/22
摘要： The instant invention is a cure system for halogenated elastomer compositions, a curable halogenated elastomer composition, and a method for curing a halogenated elastomer composition. The cure system for halogenated elastomer compositions includes a polymercapto crosslinking agent, an inorganic base, and a hydrated salt selected from the group consisting of lithium citrate, trilithium citrate pentahydrate, trilithium citrate tetrahydrate, and monolithium dihydrogen citrate monohydrate. The curable halogenated elastomer composition includes a chlorinated elastomer, and a cure system including a polymercapto crosslinking agent, an inorganic base, and a hydrated salt selected from the group consisting of lithium citrate, trilithium citrate pentahydrate, trilithium citrate tetrahydrate, and monolithium dihydrogen citrate monohydrate. Furthermore, the method for curing a halogenated elastomer composition includes the following steps: (1) providing a chlorinated elastomer composition; (2) providing a cure system composition including a polymercapto crosslinking agent, an inorganic base, and a hydrated salt selected from the group consisting of lithium citrate, trilithium citrate pentahydrate, trilithium citrate tetrahydrate, and monolithium dihydrogen citrate monohydrate; (3) uniformly blending the cure system into the chlorinated elastomer composition; (4) thereby forming a curable chlorinated elastomer composition; (5) subjecting the curable chlorinated elastomer composition to heat or heat and pressure; and (6) thereby curing the curable chlorinated elastomer composition.
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公开(公告)号：EP1833901A1
公开(公告)日：2007-09-19
申请号：EP05855094.8
申请日：2005-12-21
CPC分类号： C08K5/0091 , C08K5/0025 , C08K5/17 , C08L11/00 , C08L27/12
摘要： The invention provides compositions comprising nitrogen containing chelating agents, which can be used to reduce the effects of zinc contamination on the vulcanization rates of polymercapto based cure systems for halogenated elastomers. Such chelating agents are effective at eliminating vulcanization rate inconsistencies due to zinc contamination, without inducing negative changes to the vulcanization reaction or the subsequent physical properties of the halogenated elastomer vulcanizate. The invention also provides methods of curing a halogenated elastomer using the inventive compositions, and for articles prepared from the same.
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4.发明授权A CURE SYSTEM FOR HALOGENATED ELASTOMER COMPOSITIONS, A CURABLE HALOGENATED ELASTOMER COMPOSITION, AND A METHOD FOR CURING HALOGENATED ELASTROMER COMPOSITIONS 有权硫化体系卤化弹性体组合物可固化卤化弹性组合物和方法用于治疗卤化弹性体组合物
公开(公告)号：EP1960462B1
公开(公告)日：2010-01-13
申请号：EP07853513.5
申请日：2007-08-21
IPC分类号： C08K3/22 , C08K3/24 , C08K5/092 , C08K5/098 , C08K5/17 , C08K5/18 , C08K5/46 , C08K5/47 , C08K5/49 , C08K5/50 , C08K5/3415 , C08K5/3432 , C08K5/3445 , C08K5/36 , C08K5/09
CPC分类号： C08K5/0025 , C08K5/098 , C08K5/47 , C08L23/286 , C08L81/00 , C08L2312/00 , C08L11/00 , C08L2666/22
摘要： The instant invention is a cure system for halogenated elastomer compositions, a curable halogenated elastomer composition, and a method for curing a halogenated elastomer composition. The cure system for halogenated elastomer compositions includes a polymercapto crosslinking agent, an inorganic base, and a hydrated salt selected from the group consisting of lithium citrate, trilithium citrate pentahydrate, trilithium citrate tetrahydrate, and monolithium dihydrogen citrate monohydrate. The curable halogenated elastomer composition includes a chlorinated elastomer, and a cure system including a polymercapto crosslinking agent, an inorganic base, and a hydrated salt selected from the group consisting of lithium citrate, trilithium citrate pentahydrate, trilithium citrate tetrahydrate, and monolithium dihydrogen citrate monohydrate. Furthermore, the method for curing a halogenated elastomer composition includes the following steps: (1) providing a chlorinated elastomer composition; (2) providing a cure system composition including a polymercapto crosslinking agent, an inorganic base, and a hydrated salt selected from the group consisting of lithium citrate, trilithium citrate pentahydrate, trilithium citrate tetrahydrate, and monolithium dihydrogen citrate monohydrate; (3) uniformly blending the cure system into the chlorinated elastomer composition; (4) thereby forming a curable chlorinated elastomer composition; (5) subjecting the curable chlorinated elastomer composition to heat or heat and pressure; and (6) thereby curing the curable chlorinated elastomer composition.
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公开(公告)号：EP2291445A1
公开(公告)日：2011-03-09
申请号：EP09767465.9
申请日：2009-06-08
发明人： CASTELLUCCIO, Anthony, J. , DEAN, Jeffrey, J. , WANG, Alec, Y. , MILLER, Lindsey, Anne , JAIN, Pradeep , KUHLMAN, Roger, L. , TAHA, Angela, N. , GREEN, Larry, Shayne , MARCHAND, Gary, R. , EWART, Sean, W. , SIMS, Jeffrey, A. , BLASCHKE, Chris , FAILS, Brandon
CPC分类号： C08F210/14 , C08F6/02 , C08F210/16 , C08F297/08 , C08F297/083 , C08F2500/03 , C08F2500/08 , C08F2500/11 , C08F2500/12 , C08F2500/19 , C08F2500/20 , C08K5/098 , C08K5/12 , C08K5/17 , C08K5/52 , C08L23/0815 , C08L53/00 , C08L2666/02
摘要： Improved reaction processes comprise reacting a mixture to form a product comprising a metal alkyl, metal oxide, or mixture thereof and then passing said product to a post-reactor heat exchanger. The improvement comprises one or more of the following: (1) reacting said metal alkyl compound with an acid to produce a soluble metal ester; or (2) adding an ionic surfactant; or (3) adding a mixture comprising an antioxidant to the product under conditions sufficient to avoid formation of significant amounts of insoluble metal or metal compounds derived from said metal alkyl compound; or (4) purging said post-reactor heat exchanger with an inert gas under conditions to remove metal oxide from the post-reactor heat exchanger.
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6.发明公开VULCANIZABLE CHLORINATED ELASTOMER COMPOSITIONS WITH IMPROVED PROCESSING SAFETY AND CURE RATE 有权具有改进的安全，提高治愈率硫化氯化弹性体组合物
公开(公告)号：EP1861460A2
公开(公告)日：2007-12-05
申请号：EP06836033.8
申请日：2006-03-10
IPC分类号： C08K5/3432 , C08K5/3445 , C08L23/28 , C08K5/19 , C08K5/47
CPC分类号： C08K5/34 , C08K5/46 , C08L11/00 , C08L23/286 , C08L23/28
摘要： The instant invention is an improved cure system composition and a method for curing chlorinated elastomer compositions. The cure system composition includes a polymercapto crosslinking agent, an inorganic base, and a quaternary ammonium salt. The quaternary ammonium salt has a formula selected from the group consisting of wherein R1 is an alkyl or aryl group containing between 4 and 12 carbon atoms; wherein R2 and R3 are independently alkyl or aryl groups containing between 1 and 8 carbon atoms; wherein the total number of carbon atoms on R2 and R3 are between 3 and 9; wherein R4 and R5 are methyl groups, and R6 is an alkyl group containing between 2 and 8 carbon atoms; and wherein X is an anion. The method for curing a chlorinated elastomer, composition according to instant invention includes the following steps: (1) providing a chlorinated elastomer composition; (2) providing a cure system composition as described above; (3) contacting said chlorinated elastomer composition with said cure system composition; and (4) thereby curing said chlorinated elastomer composition.
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