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1.发明授权ELASTIC FILM GRADE THERMOPLASTIC POLYMER COMPOSITIONS HAVING IMPROVED ELASTIC PERFORMANCE 有权FOR柔性薄膜的合适的热塑性聚合物组合物具有改进的回弹性能好
公开(公告)号：EP2074173B1
公开(公告)日：2010-02-10
申请号：EP07818388.6
申请日：2007-09-19
IPC分类号： C08L53/02
CPC分类号： C08L53/025 , C08K3/013 , C08K5/0016 , C08L25/04 , C08L2666/04
摘要： The present invention provides an improved block copolymer composition for extruding films having excellent stress relaxation and increased retained tension or load at elevated temperatures, as well as a film cast from this composition. The composition is comprised of (a) 100 parts by weight of a mixture of two or more hydrogenated styrenic block copolymers (HSBC's) having at least two polystyrene end-blocks and a mid-block of a polymerized diene wherein at least 80 mol % of the residual unsaturation has been hydrogenated, wherein HSBC #1 has an apparent number average molecular weight between 35,000 and 90,000 and a polystyrene content between 15 and 40 percent by weight, wherein HSBC #2 has an apparent number average molecular weight between 95,000 and 150,000 and a polystyrene content between 15 and 40 percent by weight, wherein the ration w/w of HSBC #1 versus HSBC #2 is in the range of from 8:1 to 1:8, (b) from 10 to 50 parts by weight per 100 parts by weight of polymer (phr) of a a medium molecular weight polystyrene (2) or a mixture of a low molecular weight polystyrene (1) and a medium molecular weight polystyrene (2), wherein PS (1) has a molecular weight in the range of 500 to 4,000 and PS(2) has a molecular weight in the range of 20,000 to 150,000 and wherein PS(1) and PS(2) are used in a weight ratio of 1:5 to 5:1, (c) from 3 to 50 phr of a filler, and (d) from 30 to 70 phr of a softening agent.
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2.发明公开ELASTIC FILM GRADE THERMOPLASTIC POLYMER COMPOSITIONS HAVING IMPROVED ELASTIC PERFORMANCE 有权FOR柔性薄膜的合适的热塑性聚合物组合物具有改进的回弹性能好
公开(公告)号：EP2074173A1
公开(公告)日：2009-07-01
申请号：EP07818388.6
申请日：2007-09-19
IPC分类号： C08L53/02
CPC分类号： C08L53/025 , C08K3/013 , C08K5/0016 , C08L25/04 , C08L2666/04
摘要： The present invention provides an improved block copolymer composition for extruding films having excellent stress relaxation and increased retained tension or load at elevated temperatures, as well as a film cast from this composition. The composition is comprised of (a) 100 parts by weight of a mixture of two or more hydrogenated styrenic block copolymers (HSBC's) having at least two polystyrene end-blocks and a mid-block of a polymerized diene wherein at least 80 mol % of the residual unsaturation has been hydrogenated, wherein HSBC #1 has an apparent number average molecular weight between 35,000 and 90,000 and a polystyrene content between 15 and 40 percent by weight, wherein HSBC #2 has an apparent number average molecular weight between 95,000 and 150,000 and a polystyrene content between 15 and 40 percent by weight, wherein the ration w/w of HSBC #1 versus HSBC #2 is in the range of from 8:1 to 1:8, (b) from 10 to 50 parts by weight per 100 parts by weight of polymer (phr) of a a medium molecular weight polystyrene (2) or a mixture of a low molecular weight polystyrene (1) and a medium molecular weight polystyrene (2), wherein PS (1) has a molecular weight in the range of 500 to 4,000 and PS(2) has a molecular weight in the range of 20,000 to 150,000 and wherein PS(1) and PS(2) are used in a weight ratio of 1:5 to 5:1, (c) from 3 to 50 phr of a filler, and (d) from 30 to 70 phr of a softening agent.
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公开(公告)号：EP3436490A1
公开(公告)日：2019-02-06
申请号：EP17771060.5
申请日：2017-03-22
发明人： FLOOD, John, E. , WILLIS, Carl, L. , BENING, Robert, C. , DE GROOT, Hendrik , MUYLDERMANS, Xavier, D.D.J. , WILLIAMSON, David, T. , HANDLIN, Dale, L. , DOSSETT, Robert
IPC分类号： C08F297/04 , C08L9/06 , C08L25/08 , C08L25/10
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公开(公告)号：EP2010586B1
公开(公告)日：2010-05-26
申请号：EP07724659.3
申请日：2007-04-20
发明人： MUYLDERMANS, Xavier, Daniel, Dominique, Jean , DE GROOT, Hendrik , COLCHEN, Emmanuel , SOUTHWICK, Jeffrey, G. , WRIGHT, Kathryn, J. , COIGNOUL, Emmanuelle
IPC分类号： C08F297/04 , C08L53/02
CPC分类号： C08L53/02 , C08F297/044 , C08L53/025 , C08L2666/02 , C08L2666/24
摘要： The present invention relates to a thermoplastic elastomer composition having a durometer hardness (ASTM D2240) of Shore A 30 to 90 comprising: a) 100 parts by weight of a hydrogenated styrenic block copolymer comprising at least two blocks (A) of a polymer containing 50 %wt or more monovinyl aromatic hydrocarbon units, and at least one selectively hydrogenated block (B) of a polymer containing 50 %wt or more conjugated diene units, wherein the monovinyl aromatic hydrocarbon content is in the range of from 10 to 50 wt%, based on the total weight of block copolymer, wherein the vinyl content in the initially prepared poly(conjugated diene) block (B) is in the range of from 30 to 80 %, and wherein the hydrogenated styrenic block copolymer has a degree of hydrogenation of at least 30% with respect to the residual olefinic unsaturation in the block (B), which block copolymer optionally may be mixed with a diblock copolymer having one poly(monovinyl aromatic hydrocarbon) block and one poly(conjugated diene) block , in an amount of up to 40 wt%, b) from 20 to 150 parts by weight of a polyolefin (II); and c) from 50 to 300 parts by weight of a rubber softener (III) , preferably a paraffinic processing oil; and optionally d) from 0 to 300 parts by weight of a filler, characterized in that (i) the hydrogenated styrenic block copolymer (I) has a peak average apparent molecular weight of at least 250 kg/mole (ASTM D-5296), and (ii) the polyolefin (II) is a mixture of a high density polyethylene (Ma), having a MFR at 190°C/2.16 kg of from 5 to 50 g/10 min., and of a polypropylene (lib), having a MFR at 230°C/2.16 kg of from 1 to 40 g/10 min., (ASTM D1238), in a weight ratio (HaV(IIb) of from 0.2 to 5.
摘要翻译： 本发明涉及肖氏A 30-90的肖氏硬度（ASTM D2240）的热塑性弹性体组合物，其包含：a）100重量份的氢化苯乙烯嵌段共聚物，其包含至少两个嵌段（A） ％重量或更多的单乙烯基芳烃单元和至少一个选择性氢化的含50％重量或更多共轭二烯单元的聚合物嵌段（B），其中单乙烯基芳烃的含量为10-50重量％ 基于嵌段共聚物的总重量，其中初始制备的聚（共轭二烯）嵌段（B）中的乙烯基含量为30-80％，且其中氢化苯乙烯嵌段共聚物的氢化度为 相对于嵌段（B）中的残余烯属不饱和度至少为30％，该嵌段共聚物任选地可以与具有一个聚（单乙烯基芳烃）嵌段和一个聚（单乙烯基芳烃）嵌段的二嵌段共聚物混合， 共轭二烯）嵌段，其量为至多40重量％，b）20至150重量份的聚烯烃（II）; 和c）50至300重量份的橡胶软化剂（III），优选石蜡加工油; 其特征在于（i）氢化苯乙烯嵌段共聚物（I）的峰值平均表观分子量为至少250kg / mol（ASTM D-5296），和（ii）0-300重量份填料， 和（ii）聚烯烃（II）是在190℃/ 2.16kg下的MFR为5至50g / 10min的高密度聚乙烯（Ma）和聚丙烯（IIb）的混合物， 在230℃/ 2.16kg下的MFR为1-40g / 10min，（ASTM D1238），重量比（HaV（IIb）为0.2-5）。
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公开(公告)号：EP2010586A1
公开(公告)日：2009-01-07
申请号：EP07724659.3
申请日：2007-04-20
发明人： MUYLDERMANS, Xavier, Daniel, Dominique, Jean , DE GROOT, Hendrik , COLCHEN, Emmanuel , SOUTHWICK, Jeffrey, G. , WRIGHT, Kathryn, J. , COIGNOUL, Emmanuelle
IPC分类号： C08F297/04 , C08L53/02
CPC分类号： C08L53/02 , C08F297/044 , C08L53/025 , C08L2666/02 , C08L2666/24
摘要： The present invention relates to a thermoplastic elastomer composition having a durometer hardness (ASTM D2240) of Shore A 30 to 90 comprising: a) 100 parts by weight of a hydrogenated styrenic block copolymer comprising at least two blocks (A) of a polymer containing 50 %wt or more monovinyl aromatic hydrocarbon units, and at least one selectively hydrogenated block (B) of a polymer containing 50 %wt or more conjugated diene units, wherein the monovinyl aromatic hydrocarbon content is in the range of from 10 to 50 wt%, based on the total weight of block copolymer, wherein the vinyl content in the initially prepared poly(conjugated diene) block (B) is in the range of from 30 to 80 %, and wherein the hydrogenated styrenic block copolymer has a degree of hydrogenation of at least 30% with respect to the residual olefinic unsaturation in the block (B), which block copolymer optionally may be mixed with a diblock copolymer having one poly(monovinyl aromatic hydrocarbon) block and one poly(conjugated diene) block , in an amount of up to 40 wt%, b) from 20 to 150 parts by weight of a polyolefin (II); and c) from 50 to 300 parts by weight of a rubber softener (III) , preferably a paraffinic processing oil; and optionally d) from 0 to 300 parts by weight of a filler, characterized in that (i) the hydrogenated styrenic block copolymer (I) has a peak average apparent molecular weight of at least 250 kg/mole (ASTM D-5296), and (ii) the polyolefin (II) is a mixture of a high density polyethylene (Ma), having a MFR at 190°C/2.16 kg of from 5 to 50 g/10 min., and of a polypropylene (lib), having a MFR at 230°C/2.16 kg of from 1 to 40 g/10 min., (ASTM D1238), in a weight ratio (HaV(IIb) of from 0.2 to 5.
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