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公开(公告)号:EP0165574A2
公开(公告)日:1985-12-27
申请号:EP85107397.3
申请日:1985-06-14
发明人: Kita, Yuichi , Sakamoto, Kentaro , Baba, Masao , Okubo, Atsushi
IPC分类号: C07D207/448
CPC分类号: C07D207/448
摘要: A method for the production of maleimides, which comprises subjecting maleinamic acids to ring-closure imidation in an organic solvent capable of forming an azeotrope with water in the presence of an acid catalyst at a temperature in the range of 120° to 250°C while removing the formed water in the form of an azeotrope with said organic solvent and thereafter purifying the produced maleimides.
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公开(公告)号:EP0213933A3
公开(公告)日:1987-11-19
申请号:EP86306648
申请日:1986-08-28
IPC分类号: C07D207/448
CPC分类号: C07D207/448 , Y02P20/584
摘要: A method for the manufacture of a maleimide comprising the steps of heating a maleinamic acid in an organic solvent capable of forming an azeotrope with water in the presence of an acid catalyst while causing the water formed during the course of said reaction to be removed from the reaction system in the form of an azeotrope with said organic solvent thereby effecting ring-closure imidation of said maleinamic acid, which method is characterized by separating and recovering an acid catalyst layer from the organic solvent layer after completion of said ring-closure imidation and circulating said acid catalyst layer to the step of said ring-closure imidation for repeated use therein.
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公开(公告)号:EP0230597B1
公开(公告)日:1992-04-08
申请号:EP86117385.4
申请日:1986-12-13
发明人: Tobo, Tomoaki , Kita, Yuichi , Sakamoto, Kentro , Baba, Masao
IPC分类号: C07D207/448 , C07D207/452
CPC分类号: C07D207/448 , C07D207/452
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公开(公告)号:EP0230597A3
公开(公告)日:1988-05-25
申请号:EP86117385
申请日:1986-12-13
发明人: Tobo, Tomoaki , Kita, Yuichi , Sakamoto, Kentro , Baba, Masao
IPC分类号: C07D207/448 , C07D207/452
CPC分类号: C07D207/448 , C07D207/452
摘要: A method for inhibiting polymerization of a maleimide, which comprises adding to said maleimide, as a polymerization inhibitor, at least one compound selected from the group consisting of thiodipropionic esters, 4-t-butyl-catechol, 2,6-di-t-butyl-p-cresol,2,5-di-t-butyl-hydroquinone, 2-t-butyl-hydroquinone, 2,4-bis-(n-octylthio)-6-(4-hydroxy-3,5-di-t-butylanilino)-1,3,5-trizaine, 2,2'-thiobis(4-methyl-6-t-butylphenol), 4,4'-thiobis-16-t-butyl-m-cresol), and triethyleneglycol-bis-[3-(3-t-butyl-5-methyl-4-hydroxyphenyl) propionate].
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公开(公告)号:EP0165574B1
公开(公告)日:1992-08-19
申请号:EP85107397.3
申请日:1985-06-14
发明人: Kita, Yuichi , Sakamoto, Kentaro , Baba, Masao , Okubo, Atsushi
IPC分类号: C07D207/448
CPC分类号: C07D207/448
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公开(公告)号:EP0165574A3
公开(公告)日:1988-05-25
申请号:EP85107397
申请日:1985-06-14
发明人: Kita, Yuichi , Sakamoto, Kentaro , Baba, Masao , Okubo, Atsushi
IPC分类号: C07D207/448
CPC分类号: C07D207/448
摘要: A method for the production of maleimides, which comprises subjecting maleinamic acids to ring-closure imidation in an organic solvent capable of forming an azeotrope with water in the presence of an acid catalyst at a temperature in the range of 120° to 250°C while removing the formed water in the form of an azeotrope with said organic solvent and thereafter purifying the produced maleimides.
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公开(公告)号:EP0230597A2
公开(公告)日:1987-08-05
申请号:EP86117385.4
申请日:1986-12-13
发明人: Tobo, Tomoaki , Kita, Yuichi , Sakamoto, Kentro , Baba, Masao
IPC分类号: C07D207/448 , C07D207/452
CPC分类号: C07D207/448 , C07D207/452
摘要: A method for inhibiting polymerization of a maleimide, which comprises adding to said maleimide, as a polymerization inhibitor, at least one compound selected from the group consisting of thiodipropionic esters, 4-t-butyl-catechol, 2,6-di-t-butyl-p-cresol,2,5-di-t-butyl-hydroquinone, 2-t-butyl-hydroquinone, 2,4-bis-(n-octylthio)-6-(4-hydroxy-3,5-di-t-butylanilino)-1,3,5-trizaine, 2,2'-thiobis(4-methyl-6-t-butylphenol), 4,4'-thiobis-16-t-butyl-m-cresol), and triethyleneglycol-bis-[3-(3-t-butyl-5-methyl-4-hydroxyphenyl) propionate].
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