公开(公告)号：EP0215278A1

公开(公告)日：1987-03-25

申请号：EP86110987.4

申请日：1986-08-08

申请人： THE FIRESTONE TIRE & RUBBER COMPANY

发明人： Cole, William A. ,  Dembek, Joseph A., Jr. ,  Sagar, Vispi R.

IPC分类号： C08G79/02

CPC分类号： C08G79/025

摘要： Low or no chlorine content poly(aryloxyphosphazene) copolymers useful for fireproof foams are surprisingly produced in a one step process without use of excess phenoxide reactant over a shorter than conventional time period by (a) adding linear (NPCl 2 ) n to a mixture of phenoxides comprising alkali or alkaline earth metal phenoxide, alkylphenoxide and allylphenoxide in quantities such that the total of the phenoxides is the equivalent of the total chlorine atoms in the (NPCl 2 ) n and allylphenoxide is present in an amount equivalent to from about 2% to about 10% of the chlorine atoms in the (NPCl 2 ) n ; and (b) reacting the admixture formed in step (a) at a temperature ranging from about 280°F. to about 320°F. for a time period ranging from about 7 hours to about 10 hours.

摘要翻译： （a）将直链（NPCl2）n加入到酚氧化物的混合物中，用一步法生产用于防火泡沫的低含量或不含氯含量的聚（芳氧基磷腈）共聚物，而不使用过量的酚盐反应物 包含碱金属或碱土金属酚盐，烷基酚盐和烯丙基酚盐，其量使得总量为（NPCl2）n和烯丙基酚盐中总氯原子的当量，其量等于约2％至约10 （NPCl2）n中氯原子的百分比; 和（b）使步骤（a）中形成的混合物在约280°F的温度下反应。 到大约320°F。 持续约7小时至约10小时的时间段。