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公开(公告)号：EP2519350B1
公开(公告)日：2019-03-20
申请号：EP10840586.1
申请日：2010-12-30
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2.发明公开HIGHLY ACTIVE METATHESIS CATALYSIS SELECTIVE FOR ROMP AND RCM 审中-公开FÜRROMP UND RCM SELEKTIVE HOCHAKTIVE METATHESEKATALYSATOREN
公开(公告)号：EP2519350A1
公开(公告)日：2012-11-07
申请号：EP10840586.1
申请日：2010-12-30
CPC分类号： C07F15/0046 , B01J31/2269 , B01J31/2278 , B01J2231/54 , B01J2531/821 , C07C233/58 , C07C255/54 , C07D207/20 , C07D207/34 , C08G61/08 , C08G2261/418
摘要： A kind of novel carbene ligand and corresponding novel ruthenium catalyst are provided. The ruthenium catalysts are highly active and selective for ROMP and RCM reactions. The significant electronic effects of different substituted carbene ligands on the catalytic activity and stability of corresponding carbene ruthenium complexes are disclosed. The methods for preparing new ruthenium complexes are disclosed. Moreover, efficient methods for making various functional polymers and quality modified nitrile butadiene rubbers via different metathesis and hydrogenation reactions in the presence of the new ruthenium catalysts are provided.
摘要翻译： 本发明涉及一种新的卡宾配体和相应的新的钌催化剂，其对ROMP和RCM反应具有高度活性和选择性。 它公开了不同取代的卡宾配体对相应的卡宾钌配合物的催化活性和稳定性的显着电子效应; 本发明中的一些新型钌络合物可广泛用作催化剂，对ROMP和RCM反应具有极高的选择性。 本发明还涉及新的钌配合物的制备和复分解的用途。 此外，本发明还提供了在新的钌催化剂存在下通过不同的复分解和氢化反应制备各种官能聚合物和质量改性的丁腈橡胶的有效方法。
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3.发明公开
公开(公告)号：EP4215556A1
公开(公告)日：2023-07-26
申请号：EP21868670.7
申请日：2021-09-16
IPC分类号： C08F236/12 , C08F8/04
摘要： Disclosed are a liquid hydrogenated nitrile-butadiene rubber, a preparation method therefor and the use thereof. In the liquid hydrogenated nitrile-butadiene rubber: the content of acrylonitrile is 15-50%; the hydrogenation saturation is 75-99.5%; the weight-average molecular weight (Mw) is 3,000-60,000; the molecular weight polydispersity index (PDI) is 2.0-8.0; and the glass transition temperature (Tg) is lower than -28°C. The liquid hydrogenated nitrile-butadiene rubber is low in molecular weight and wide in molecular weight polydispersity, simultaneously has an excellent fluidity during processing and excellent mechanical properties after curing, and has a unique application value in the field of special rubbers; and the preparation method therefor is simple and feasible in terms of the process.
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公开(公告)号：EP3064272B1
公开(公告)日：2018-11-28
申请号：EP16164005.7
申请日：2010-12-30
CPC分类号： C07F15/0046 , B01J31/2269 , B01J31/2278 , B01J2231/54 , B01J2531/821 , C07C233/58 , C07C255/54 , C07D207/20 , C07D207/34 , C08G61/08 , C08G2261/418
摘要： The present invention relates to a kind of novel carbene ligands and corresponding new ruthenium catalysts, which are highly active and selective for ROMP and RCM reactions. It discloses the significant electronic effect of different substituted carbene ligands on the catalytic activity and stability of corresponding carbene ruthenium complexes; some of novel ruthenium complexes in the invention can be broadly used as catalysts highly effectively and selective for ROMP and RCM reactions. The invention also relates to preparation of new ruthenium complexes and the use in metathesis. Moreover, the invention also provides efficient methods of making various functional polymers and quality-modified nitrile butadiene rubbers by different metathesis and hydrogenation reactions in the presence of the new ruthenium catalysts.
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5.发明公开HIGHLY ACTIVE METATHESIS CATALYSTS SELECTIVE FOR ROMP AND RCM REACTIONS 审中-公开HOCHAKTIVE METATHESEKATALYSATOREN，DIEFÜRROMP- UND RCM-REAKINGEN SELEKTIV SIND
公开(公告)号：EP3064272A1
公开(公告)日：2016-09-07
申请号：EP16164005.7
申请日：2010-12-30
CPC分类号： C07F15/0046 , B01J31/2269 , B01J31/2278 , B01J2231/54 , B01J2531/821 , C07C233/58 , C07C255/54 , C07D207/20 , C07D207/34 , C08G61/08 , C08G2261/418
摘要： The present invention relates to a kind of novel carbene ligands and corresponding new ruthenium catalysts, which are highly active and selective for ROMP and RCM reactions. It discloses the significant electronic effect of different substituted carbene ligands on the catalytic activity and stability of corresponding carbene ruthenium complexes; some of novel ruthenium complexes in the invention can be broadly used as catalysts highly effectively and selective for ROMP and RCM reactions. The invention also relates to preparation of new ruthenium complexes and the use in metathesis. Moreover, the invention also provides efficient methods of making various functional polymers and quality-modified nitrile butadiene rubbers by different metathesis and hydrogenation reactions in the presence of the new ruthenium catalysts.
摘要翻译： 本发明涉及一种新的卡宾配体和相应的新的钌催化剂，其对ROMP和RCM反应具有高度活性和选择性。 它公开了不同取代的卡宾配体对相应的卡宾钌配合物的催化活性和稳定性的显着电子效应; 本发明中的一些新型钌络合物可广泛用作催化剂，对ROMP和RCM反应具有极高的选择性。 本发明还涉及新的钌配合物的制备和复分解的用途。 此外，本发明还提供了在新的钌催化剂存在下通过不同的复分解和氢化反应制备各种官能聚合物和质量改性的丁腈橡胶的有效方法。
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