SILANE COMPOUND CONTAINING PERFLUORO(POLY)ETHER GROUP

    公开(公告)号:EP2915833B1

    公开(公告)日:2018-06-06

    申请号:EP13852235.4

    申请日:2013-10-31

    摘要: The present invention provides a perfluoro(poly)ether group containing silane compound which is able to form a layer having water-repellency, oil-repellency and antifouling property as well as high friction durability, and represented by the formula (1a) or the formula (1b): €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒA - Rf - X - SiQ k Y 3-k –ª–ª–ª€ƒ€ƒ€ƒ€ƒ€ƒ(1a) €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒY 3 - k Q k Si-X-Rf-X- SiQ k Y 3-k –ª–ª–ª€ƒ€ƒ€ƒ€ƒ€ƒ(1b) wherein A represents a C 1-16 alkyl which may be substituted by one or more fluorine atoms; Rf represents -(OC 9 F 8 ) a -(OC 3 F 6 ) b -(OC 2 F 4 ) c -(OCF 2 ) d -wherein a, b, c and d are each independently an integer of 0 or more and 200 or less, the sum of a, b, c and d is 1 or more and the occurrence order of the respective repeating units in parentheses with the subscript a, b, c or d is not limited in the formula; X represents a divalent organic group; Y represents, each independently at each occurrence, a hydroxyl group, a hydrolyzable group, or a hydrocarbon group; Q represents, each independently at each occurrence,-Z-SiR 1 n R 2 3 - n ; Z represents, each independently at each occurrence, a divalent organic group: with the proviso that Z is not a group which forms a siloxane bond together with a Si atom present in the end of a molecular backbone of the formula (1a) or the formula (1b), R 1 represents, each independently at each occurrence, a hydroxyl group or a hydrolyzable group; R 2 represents, each independently at each occurrence, a C 1-22 alkyl group or Q'; Q' has the same definition as that of Q; n is, each independently in each Q and Q', an integer selected from 0-3, and the total sum of n one or more; in Q, the number of Si atoms which are straightly linked via the Z group is up to five; k is an integer each independently selected from 1-3.

    PROCESS FOR PREPARING FLUORINE-CONTAINING PROPENE BY GAS-PHASE FLUORINATION
    14.
    发明授权
    PROCESS FOR PREPARING FLUORINE-CONTAINING PROPENE BY GAS-PHASE FLUORINATION 有权
    气相氟化制备含氟丙烯的方法

    公开(公告)号:EP2318338B8

    公开(公告)日:2013-12-18

    申请号:EP09787978.7

    申请日:2009-06-25

    IPC分类号: C07C17/21 C07C17/20 C07C21/18

    摘要: The present invention provides a process for preparing a fluorine-containing propene represented by the chemical formula CF3CF═CX1X2, wherein X1 is a hydrogen atom or chlorine atom, and X2 is a fluorine atom, chlorine atom, or hydrogen atom, by reacting a halogenated propene represented by the chemical formula CCIYZCF═CX1X2, wherein X1 and X2 are the same as above, and Y and Z may be the same or different and individually indicate a fluorine atom or chlorine atom, with anhydrous hydrogen fluoride in a gas phase in the presence of a chromium oxide or a fluorinated chromium oxide as a fluorination catalyst. The process of the present invention provides a fluorine-containing propene represented by the chemical formula CF3CF═CClX, wherein X is Cl, H or F, under relatively mild conditions at a high yield.

    摘要翻译: 本发明提供了一种制备由化学式CF3CF═ CX1X2表示的含氟丙烯的方法,其中X1是氢原子或氯原子,X2是氟原子,氯原子或氢原子,通过卤化 由化学式CCIYZCF═ CX1X2表示的丙烯,其中X 1和X 2与上述相同,并且Y和Z可以相同或不同,并且各自表示氟原子或氯原子,无水氟化氢在气相中 作为氟化催化剂存在氧化铬或氟化氧化铬。 本发明的方法在相对温和的条件下以高收率提供了由化学式CF3CF═ CClX(其中X为Cl,H或F)表示的含氟丙烯。

    SILANE COMPOUND CONTAINING PERFLUORO(POLY)ETHER GROUP
    15.
    发明公开
    SILANE COMPOUND CONTAINING PERFLUORO(POLY)ETHER GROUP 有权
    硅烷化合物具有全氟(聚)醚

    公开(公告)号:EP2915833A1

    公开(公告)日:2015-09-09

    申请号:EP13852235.4

    申请日:2013-10-31

    摘要: The present invention provides a perfluoro(poly)ether group containing silane compound which is able to form a layer having water-repellency, oil-repellency and antifouling property as well as high friction durability, and represented by the formula (1a) or the formula (1b):

            A - Rf - X - SiQ k Y 3-k ▪▪▪     (1a)

            Y 3 - k Q k Si-X-Rf-X- SiQ k Y 3-k ▪▪▪     (1b)

    wherein A represents a C 1-16 alkyl which may be substituted by one or more fluorine atoms;
    Rf represents -(OC 9 F 8 ) a -(OC 3 F 6 ) b -(OC 2 F 4 ) c -(OCF 2 ) d -wherein a, b, c and d are each independently an integer of 0 or more and 200 or less, the sum of a, b, c and d is 1 or more and the occurrence order of the respective repeating units in parentheses with the subscript a, b, c or d is not limited in the formula;
    X represents a divalent organic group;
    Y represents, each independently at each occurrence, a hydroxyl group, a hydrolyzable group, or a hydrocarbon group;
    Q represents, each independently at each occurrence,-Z-SiR 1 n R 2 3 - n ;
    Z represents, each independently at each occurrence, a divalent organic group: with the proviso that Z is not a group which forms a siloxane bond together with a Si atom present in the end of a molecular backbone of the formula (1a) or the formula (1b),
    R 1 represents, each independently at each occurrence, a hydroxyl group or a hydrolyzable group;
    R 2 represents, each independently at each occurrence, a C 1-22 alkyl group or Q';
    Q' has the same definition as that of Q;
    n is, each independently in each Q and Q', an integer selected from 0-3, and the total sum of n one or more;
    in Q, the number of Si atoms which are straightly linked via the Z group is up to five;
    k is an integer each independently selected from 1-3.

    METHOD FOR PRODUCING OLEFIN
    17.
    发明授权
    METHOD FOR PRODUCING OLEFIN 有权
    用于生产烯烃

    公开(公告)号:EP2078709B1

    公开(公告)日:2011-12-14

    申请号:EP07830680.0

    申请日:2007-10-26

    IPC分类号: C07C17/23 C07C21/18

    CPC分类号: C07C17/23 C07C19/08 C07C21/18

    摘要: Disclosed is a method for producing an olefin represented by the following general formula (II): RfCF=CH2 (wherein Rf is as defined below), which is characterized in that a dehalogenation reaction is performed by bringing a fluorohalide represented by the following general formula (I): RfCF2CH2X (wherein Rf represents H(CF2)n (n = 1-8) or F(CF2)n (n = 1-8), and X represents Br or I) into contact with a metal in a reaction medium which is composed a polar organic solvent, or a mixed solvent of water and a polar organic solvent. This method enables to produce an olefin at low cost with good selectivity and high yield under relatively mild reaction conditions.