摘要:
Three types of trisiloxane surfactants having the basic formula: MDM' are described wherein the substituents on the differing M and M' groups, in conjunction with pendant polyalkylene oxide substituents on the D group render the surfactant resistant to hydrolysis under either basic or acidic conditions outside the pH range of 6.0 to 7.5. The compositions are useful in agricultural, household and cosmetic applications.
摘要:
Compositions comprising disiloxane surfactant compositions comprising a silicone composition comprising a silicone having the formula: MM' where M = R1R2R3SiO1/2; M' = R4R5R6SiO1/2; with R1 selected from the group consisting of branched monovalent hydrocarbon radical of from 3 to 6 carbon atoms and R7, where R7 has the formula: R8R9R10SiR12 with R8, R9, and R10 each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms and monovalent aryl or alkaryl hydrocarbon radicals having from 6 to 13 carbon atoms and R12 is a divalent hydrocarbon radical having from 1 to 3 carbon atoms, R2 and R3 are each independently selected from the group of from 1 to 6 carbon atom monovalent hydrocarbon radicals or R1, with R4 an alkylpolyalkyleneoxide of the general formula: R13(C2H4O)a(C3H6O)b(C4H8O)cR14 where R13 is a divalent linear or branched hydrocarbon radical having the structure: -CH2-CH(R15)(R16)dO- where R15 is H or methyl; R16 is a divalent alkyl radical of 1 to 6 carbons where the subscript d may be 0 or 1; R14 is selected from the group consisting of H, monovalent hydrocarbon radicals of from 1 to 6 carbon atoms and acetyl where the subscripts a, b and c are zero or positive and satisfy the following relationships: 2 ≤ a + b + c ≤ 20 with a ≥ 2, and R5 and R6 are each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms or R4 that exhibit resistance to hydrolysis over a wide pH range.
摘要:
The present invention provides for a composition comprising a siloxane having the formula: M 1 D M 2 wherein M 1 = (R 1 )(R 2 )(R 3 )SiO 1/2 ; M 2 = (R 4 )(R 5 )(R 6 ) SiO 1/2 and D = (R 7 )(Z) SiO 2/2 where R 1 , R 2 , R 3 R 4 , R 5 , R 6 and R 7 are each independently selected from the group consisting of 1 to 4 carbon monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 4 to 9 carbons containing an aryl group; Z is a pendant hydrophilic ionic group selected from the group consisting of R 8 -R A , R 9 R c and R 10 -R Z ; R A being an anionic substituent, R c a cationic substituent or R z a zwitterionic substituent on the D group wherein the composition is resistant to hydrolysis under either basic or acidic conditions.
摘要:
Compositions comprising an asymmetric disiloxane surfactant composition comprising a silicone composition comprising a silicone having the formula: MM’ where M or M' comprises an alkylpolyalkyleneoxide bearing substituent selected from the group consisting of: R13(C2H4O)a(C3H6O)b(C4H8O)cR14 and R12SiR5R6(R13(C2H4O)a(C3H6O)b(C4H8O)cR14) that exhibit resistance to hydrolysis over a wide pH range.
摘要:
Compositions comprising an asymmetric disiloxane surfactant composition comprising a silicone composition comprising a silicone having the formula MM' where M or M' comprises an alkylpolyalkyleneoxide bearing substituent selected from the group consisting of: R13(C2H4O)a(C3H6O)b(C4H8O)cR14 and R12SiR5R6(R13(C2H4O)a(C3H6O)b(C4H8O)cR14) that exhibit resistance to hydrolysis over a wide pH range.
摘要翻译:包含不对称二硅氧烷表面活性剂组合物的组合物,所述组合物包含硅氧烷组合物,所述硅氧烷组合物包含具有式MM'的硅氧烷,其中M或M'包含带有选自R13(C2H4O)a(C3H6O)b(C4H8O)cR14的烷基聚氧化烯烃基取代基和 R 12 SiR 5 R 6(R 13(C 2 H 4 O)a(C 3 H 6 O)b(C 4 H 8 O)c R 14),其在宽pH范围内表现出对水解的抗性。