摘要:
The present invention has for its object to provide a novel organic zinc catalyst showing very high polymerizing activity in the reaction for producing a poly(alkylene carbonate) from carbon dioxide and an epoxide as well as a method of producing a poly(alkylene carbonate) using the same. The present invention provides an organic zinc catalyst to be used for the reaction for producing a poly(alkylene carbonate) from carbon dioxide and an epoxide, which is obtained by reacting a zinc compound, an aliphatic dicarboxylic acid and an aliphatic monocarboxylic acid in a mole ratio of 0.0001 to 0.1 relative to the aliphatic dicarboxylic acid.
摘要:
The present invention relates to a crosslinked poly(meth)acrylic acid nitroxide compound resulting from crosslinking of a poly(meth)acrylic acid nitroxide compound, and an object of the present invention is to provide a method of inexpensively and easily producing a crosslinked poly (meth) acrylic acid nitroxide compound having a high radical concentration. The present invention is a method of producing a crosslinked poly(meth)acrylic acid nitroxide compound including a repeating unit represented by the general formula (2) :
(in the formula, R represents a hydrogen atom or a methyl group), comprising a nitroxidation step carried out in a state that a crosslinked poly(meth)acrylic acid imino compound resulting from crosslinking of a poly(meth)acrylic acid imino compound including a repeating unit represented by the general formula (1):
(in the formula, R represents the same group as that represented by R in said general formula (2)) is dispersed in water.