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21.发明授权
公开(公告)号：EP2825288B1
公开(公告)日：2020-07-22
申请号：EP13713879.8
申请日：2013-04-02
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22.发明公开
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23.发明授权
公开(公告)号：EP2938424B1
公开(公告)日：2018-03-21
申请号：EP14700894.0
申请日：2014-01-17
发明人： FISCHER, Björn , HAUKE, Stefan , JOH, Ralph , KINZL, Markus , SCHNEIDER, Rüdiger
CPC分类号： B01D9/0031 , B01D9/0004 , B01D53/1425 , B01D53/1475 , B01D53/1493 , B01D53/62 , B01D53/96 , B01D2252/20494 , B01D2257/504 , B01D2258/0283 , B01D2259/122 , Y02A50/2342 , Y02C10/06
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公开(公告)号：EP3271046A1
公开(公告)日：2018-01-24
申请号：EP16710937.0
申请日：2016-03-07
摘要： The invention relates to a method for the desulphurisation of a hydrogen sulphide-containing gas flow (3), in particular a gas flow that can be used for combustion in a gas turbine (23), wherein the gas flow (3) is brought into contact with a washing agent (7) containing a catalytically active component (17) for the absorption of the hydrogen sulphide and forming elementary sulphur, wherein the catalytically active component (17) is reduced in the formation of the elementary sulphur, wherein the washing medium (7) containing the reduced catalytically active component (17) is supplied to a regeneration stage (11), in which the reduced catalytically active component (17) is converted back via oxidation with an oxygen-containing gas (19) supplied to the regeneration stage (11), and wherein the oxygen-containing gas (19) is supplied to the regeneration stage (11) from a compressor (21) of a gas turbine (23). By means of a method of this type, air from the compressor (21) of a gas turbine (23) is used for purifying a washing medium used for the desulphurisation of a gas flow. The invention also relates to a suitable device (1) for this purpose.
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25.发明授权
公开(公告)号：EP2637758B1
公开(公告)日：2018-01-17
申请号：EP11788395.9
申请日：2011-11-08
CPC分类号： B01D53/96 , B01D9/0013 , B01D9/0054 , B01D53/1425 , B01D53/1475 , B01D2009/0086 , B01D2251/104 , B01D2251/106 , B01D2251/306 , B01D2251/604 , B01D2251/606 , B01D2252/20484 , B01D2252/20494 , B01D2257/504 , C01B17/56 , Y02C10/06 , Y02P20/152
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26.发明公开
公开(公告)号：EP2964364A1
公开(公告)日：2016-01-13
申请号：EP14707959.4
申请日：2014-02-18
发明人： BRECHTEL, Kevin , JOH, Ralph , KINZL, Markus , NICKELFELD, Hans, Wolfgang , RAAKE, Katrin , RENGER, Matthias , SCHRAMM, Henning
CPC分类号： B01D53/1493 , B01D53/1418 , B01D53/1425 , B01D53/1462 , B01D53/1468 , B01D2252/20494 , B01D2252/602 , B01D2257/304 , B01D2258/05 , C01B17/05 , C02F1/725 , C02F1/727 , C02F1/74 , C02F2101/101 , C02F2103/18 , C02F2303/16 , C10L3/103 , Y02P20/152 , Y02P20/584
摘要： The invention relates to an absorbent which comprises a dissolved amino acid salt and a dissolved metal. The absorbent is brought into contact with the acidic gas in an absorber. In the absorber, the H2S converts from the gas phase to the liquid phase. In addition, carbon dioxide (CO2) is likewise absorbed from the gas as a function of the contact time. The washing solution is passed from the absorber to a regeneration tank. In the regeneration tank, the solution is gassed with air, oxygen (O2)-enriched air or with pure O2. By introducing O2 into the solution, the H2S already present in the solution is reacted over the dissolved metal catalyst. After the regeneration, possible solids are separated off and the regenerated washing solution is returned to the absorber.
摘要翻译： 吸收介质包含溶解的氨基酸盐和溶解的金属。 吸收介质是在吸收体接触与酸性气体。 在吸收器中，H 2 S从气相到液相越过。 此外，二氧化碳（CO 2）被从气体同样吸收为的接触时间的函数。 所述洗涤溶液从吸收器到再生罐输送。 在再生槽，将溶液与处理过的空气，与氧（O 2） - 富集的空气或纯氧气。 作为引入的O 2到溶液中的结果，存在于溶液中的H 2 S在溶解的金属催化剂进行反应。 在再生之后，可以固体分离出并再生的洗涤液被再循环到吸收器。
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27.发明公开AMINHALTIGE WASCHLÖSUNG MIT OZON UND/ODER WASSERSTOFFPEROXID ZUR ABSORPTION VON KOHLENDIOXID 审中-公开阿明含臭氧和/或氢气清洗溶液吸收二氧化碳
公开(公告)号：EP2854996A1
公开(公告)日：2015-04-08
申请号：EP13735242.3
申请日：2013-07-03
发明人： FISCHER, Björn , HAUKE, Stefan , JOH, Ralph , KINZL, Markus , KUETTEL, Diego Andres , KURSAWE, Ansgar , SCHNEIDER, Rüdiger
CPC分类号： B01D53/62 , B01D53/1475 , B01D53/1493 , B01D53/56 , B01D2251/104 , B01D2251/106 , B01D2252/204 , B01D2252/20478 , B01D2252/20494 , B01D2252/60 , B01D2252/602 , B01D2257/504 , B01D2258/0283 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： The invention relates to a method for depositing carbon dioxide from a flue gas (RG) of a combustion system. A scrubbing solution (A) with an amine-containing absorption agent (for example 20) is mixed together with ozone and/or hydrogen peroxide as an oxidizing agent for nitrite. The flue gas (RG) is brought into contact with the scrubbing solution (A) prepared in this manner, whereby carbon dioxide contained in the flue gas is absorbed, and the scrubbing solution (A) is then thermally treated, whereby the carbon dioxide is desorbed. The invention further relates to a corresponding scrubbing solution (A) with an amine-containing absorption agent (for example 20) and with ozone and/or hydrogen peroxide as an oxidizing agent for nitrite.
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28.发明公开ABSCHEIDEVORRICHTUNG FÜR KOHLENDIOXID UND VERFAHREN ZU DEREN BETRIEB SOWIE ABTRENNEINHEIT 审中-公开分离用于操作和分离单元二氧化碳AND METHOD
公开(公告)号：EP2825288A1
公开(公告)日：2015-01-21
申请号：EP13713879.8
申请日：2013-04-02
摘要： A separation device (2) for carbon dioxide, particularly from a flue gas (RG) of a fossil-fuelled power plant, is specified, comprising an absorption unit (4), a desorption unit (5) associated with the absorption unit (4), and a separating unit (10) for separating salts from a scrubbing solution. The absorption unit (4) and the desorption unit (5) are connected to one another via a first line (6) for a regenerated scrubbing solution (A) and a second line (7) for a loaded scrubbing solution (A'). The separating unit (10) comprises a crystallizer (20) for forming salt crystals, and a first removal unit (25) downstream thereof for separating out the salt crystals. A corresponding method for operating the separation device (2) is also specified. In addition, a separating unit (10) for separating out salts from a scrubbing solution (10) is specified, which comprises a crystallizer (20) and a first removal unit (25) downstream thereof for separating out salt crystals. The crystallizer (20) comprises a crystallization chamber (21) for forming the salt crystals and a counter-current classifier (22) for separating the salt crystals by particle size. A first branch line (32), which runs into the counter-current classifier (22) via a second removal unit (26), is connected to the crystallization chamber (21).
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29.发明公开
公开(公告)号：EP2648828A1
公开(公告)日：2013-10-16
申请号：EP12700393.7
申请日：2012-01-12
发明人： FISCHER, Björn , JOH, Ralph , SCHNEIDER, Rüdiger
IPC分类号： B01D53/14
CPC分类号： B01D53/62 , B01D53/1475 , B01D53/1493 , Y02C10/06
摘要： The invention relates to a solvent (2) for selective absorption of CO
2 from the flue gas of a combustion plant. The solvent (2) comprises an aqueous solution of a secondary amine (4) as an active scrubbing substance and an additive (6), the additive (6) comprising a salt of vitamin C or E (3). The invention further relates to a process for providing an absorption liquid, and to the use of the solvent (2) for selective absorption of CO
2 from the flue gas of a combustion plant.-
30.发明公开
公开(公告)号：EP2595730A1
公开(公告)日：2013-05-29
申请号：EP11725703.0
申请日：2011-06-08
发明人： GOETHEER, Earl Lawrence Vincent , JOH, Ralph , GILING, Erwin Johannes Martinus , SCHNEIDER, Rüdiger , VAN DER MEER, Johannes , VERDOES, Dirk
CPC分类号： B01D53/96 , B01D53/62 , B01D2252/20494 , B01D2257/504 , Y02C10/04
摘要： The invention relates to a method (1) for treating a contaminated alkaline amino acid saline solution (3). Carbon dioxide (2) is first introduced into the amino acid saline solution (3), by means of which carbonate or carbonate salts (4) precipitate and are filtered out. The remaining filtrate is then cooled, wherein amino acids or amino acid salts (7) crystallize and are also filtered out. The amino acid or the amino acid salt (7) is then dissolved again, by means of which a treated amino acid salt solution (15) is recovered. The invention further relates to a device (30) for carrying out the method.
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