CONJUGATED DIENE PHOSPHINATE COMPOUNDS, PREPARATION METHOD AND USE THEREOF
    36.
    发明公开
    CONJUGATED DIENE PHOSPHINATE COMPOUNDS, PREPARATION METHOD AND USE THEREOF 审中-公开
    共轭DIENPHOSPHINATVERBINDUNGEN,制造方法和使用

    公开(公告)号:EP2493901A4

    公开(公告)日:2013-12-04

    申请号:EP09850743

    申请日:2009-10-30

    IPC分类号: C07F9/32 C08K5/51 C09K21/12

    摘要: This invention relates to conjugated diene phosphinate compounds for making halogen free phosphinate-containing flame retardants, inimer and metal extractants, method for preparing said compounds from unsaturated ketones or aldehydes, and the 5 use thereof. The compounds of the present invention having the following formula (III), wherein R1, R2, R3, R4, R5 and R6 represent, independently, hydrogen, alkyl, aryl, alkaryl, aralkyl, cycloalkyl, heterocycloalkyl, or alkenyl groups; R7 represents hydrogen, alkyl, aryl, alkaryl, aralkyl, cycloalkyl, alkenyl groups, or metals selected from the group consisting of Na, Li, Ca.

    PROCESS FOR PREPARING AN ORTHO-SUBSTITUTED 5-HALOPHENOL AND A SYNTHESIS INTERMEDIATE THEREOF
    39.
    发明公开
    PROCESS FOR PREPARING AN ORTHO-SUBSTITUTED 5-HALOPHENOL AND A SYNTHESIS INTERMEDIATE THEREOF 有权
    PROCEDURE FOR AN的制备邻位取代的5-卤代苯酚类合成中间体THEREOF

    公开(公告)号:EP2574192A1

    公开(公告)日:2013-04-03

    申请号:EP10851578.4

    申请日:2010-05-19

    摘要: A process for preparing a 5-halophenol, ortho-substituted by an electron-donating group, is described. Also described, is a process for preparing a sulphonic ester of an ortho-substituted phenol, which is the synthesis intermediate for the ortho-substituted 5-halophenol. The process for preparing a phenol ortho-substituted by an electron-donating group and protected in the form of a sulphonic ester can include reacting a phenol ortho-substituted by an electron-donating group with a sulphonylating agent in the presence of a Lewis acid. The process for preparing a 5-halophenol ortho-substituted by an electron-donating group can include a first step of preparing a phenol ortho-substituted by an electron-donating group and protected in the form of a sulphonic ester, as described above; a second step of halogenating the protected phenol intermediate obtained in the preceding step, in the position para to the electron-donating group; and a third step of deprotecting the sulphonic ester function to hydroxyl.