PROCESS FOR THE PREPARATION OF POROUS PROPYLENE POLYMERS
    39.
    发明公开
    PROCESS FOR THE PREPARATION OF POROUS PROPYLENE POLYMERS 有权
    VERFAHREN ZUR HERSTELLEN VONPORÖSENPROPYLENPOLYMEREN

    公开(公告)号:EP3060588A1

    公开(公告)日:2016-08-31

    申请号:EP14786901.0

    申请日:2014-10-21

    IPC分类号: C08F10/06 C08F210/06

    摘要: Process for the preparation of a porous propylene carried out in the presence of a catalyst system comprising (a) a Ziegler-Natta catalyst containing at least two electron donor compounds one of which being present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum alkyl and comprising the following steps: i) contacting the catalyst components (a) and (b) for a period of time ranging from 1 to 60 minutes, at a temperature ranging from 35 to 55°C; optionally, ii) pre-polymerizing with one or more olefins of formula CH2=CHR, where R is H or a C1-C10 hydrocarbon group, up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); and iii) polymerizing propylene in the optional presence of minor amounts of ethylene and/or C4-C10 alpha olefins producing said porous propylene (co)polymer.

    摘要翻译: 在催化剂体系存在下进行的多孔丙烯的制备方法,包括(a)含有至少两种电子给体化合物的齐格勒 - 纳塔催化剂,其中一种以50-90% 相对于供体的总量,选自琥珀酸盐,另一种选自1,3-二醚,(b)烷基铝,包括以下步骤:i)使催化剂组分(a)和(b)接触一段时间 时间为1至60分钟,温度范围为35至55℃; 任选地,ii)使用一种或多种式CH 2 = CHR的烯烃进行预聚合,其中R是H或C1-C10烃基,直到每克固体催化剂组分约0.1至约1000g的聚合物的形成量 (一个); 和iii)在少量乙烯和/或C 4 -C 10α-烯烃的任选存在下聚合丙烯,生产所述多孔丙烯(共)聚合物。

    PROCESS FOR THE PREPARATION OF PROPYLENE RANDOM COPOLYMERS
    40.
    发明公开
    PROCESS FOR THE PREPARATION OF PROPYLENE RANDOM COPOLYMERS 审中-公开
    VERFAHREN ZUR HERSTELLUNG VON RANDOM-PROPYLENCOPOLYMEREN

    公开(公告)号:EP2909244A1

    公开(公告)日:2015-08-26

    申请号:EP13773713.6

    申请日:2013-10-03

    IPC分类号: C08F210/06 C08F4/651

    摘要: A process for the preparation of random copolymer of propylene containing up to 6.0 % by weight of ethylene units, suitable for the manufacture of pipes, by copolymerizing propylene and ethylene in the presence of a catalyst system comprising the product obtained by contacting the following components: (a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) n aluminum hydrocarbyl compound, and (c) optionally an external electron donor compound.

    摘要翻译: 一种制备含有至多6.0重量%乙烯单元的丙烯的无规共聚物的方法,该乙烯单元通过在包含通过接触以下组分获得的产物的催化剂体系的存在下共聚丙烯和乙烯来制备管道: (a)固体催化剂组分,其包含卤化镁,至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物,其中一种以相对于总量为40至90摩尔%的量存在 选自琥珀酸盐,另一种选自1,3二醚,(b)n烃基铝化合物和(c)任选的外电子给体化合物。