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41.发明公开
公开(公告)号：EP2780380A1
公开(公告)日：2014-09-24
申请号：EP12783590.8
申请日：2012-11-07
发明人： GALVAN, Monica , PANTALEONI, Roberto , FUSCO, Ofelia , GADDI, Benedetta , NEUMANN, Andreas , MAZZUCCO, Antonio , COLLINA, Gianni , CIARAFONI, Marco
CPC分类号： C08L23/12 , C08F10/06 , C08F4/651 , C08F4/6543 , C08F2/00 , C08F210/16 , C08F210/06 , C08F2500/11 , C08F2500/12 , C08F2500/17 , C08F2500/21 , C08F2/001 , C08F110/06 , C08L23/16
摘要： A process for the preparation of propylene polymer compositions comprising from 50 to 90 % by weight of a propylene (co)polymer fraction insoluble in xylene at 25°C, and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25°C, said process comprising: (i) a first step of polymerizing propylene in the optional presence of ethylene and/or C 4 -C 10 alpha olefins, to produce a propylene (co)polymer being for at least 85% by weight insoluble in xylene at 25°C; and (ii) a successive step, carried out in gas-phase, in the presence of the product coming from step (i), of copolymerizing a mixture of ethylene with one or more ±-olefins CH 2 =CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce an ethylene copolymer; the process being carried out in the presence of a catalyst system comprising: the product obtained by contacting: (a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two internal electron donor compounds one of which being present in an amount from 35 to 90% by mol with respect to the total amount of donors and being selected from succinates and the other being selected from 1,3-diethers, the total amount of internal electron donor compounds being lower than 14.0% by weight with respect to the total weight of the solid catalyst component; with (b) an aluminum hydrocarbyl compound, and optionally with (c) an external electron donor compound.
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42.发明公开PROCESS FOR THE PREPARATION OF HIGH PURITY PROPYLENE POLYMERS 有权VERFAHRENFÜRDIE HERSTELLUNG VON HOCHREINEN PROPYLENPOLYMEREN
公开(公告)号：EP2758440A1
公开(公告)日：2014-07-30
申请号：EP12759441.4
申请日：2012-09-17
发明人： GALVAN, Monica , PANTALEONI, Roberto , FUSCO, Ofelia , GADDI, Benedetta , NEUMANN, Andreas , MAZZUCCO, Antonio , COLLINA, Gianni , SARTORI, Gabriella
CPC分类号： C08F10/06 , C08J5/18 , C08J2323/14 , C08F4/651 , C08F4/6543 , C08F110/06 , C08F2500/04 , C08F2500/12 , C08F2500/15
摘要： A process for the preparation of high purity propylene polymers carried out in the presence of a catalyst comprising the product obtained by contacting: (a) a solid catalyst component comprising Mg, Ti and at least a first internal electron donor compound (HD) selected among the succinates and a second internal electron donor compound (2ID) selected among the 1,3-diethers, wherein the molar ratio of first internal donor over second internal donor 1ID:2ID is comprised between 4:6 and 9:1, with (b) an organo-aluminium compound, and optionally with (c) an external electron donor compound, said process being carried out at a temperature equal or higher than 78° C. and by employing a molar ratio of organo-aluminum compound over solid catalyst component (b):(a) of lower than 5.
摘要翻译： 一种制备高纯度丙烯聚合物的方法，所述丙烯聚合物在催化剂存在下进行，所述催化剂包括通过使（a）包含Mg，Ti和至少第一内部电子给体化合物（HD）的固体催化剂组分与 所述琥珀酸盐和选自所述1,3-二醚中的第二内给电子体化合物（2ID），其中所述第一内给体相对于所述第二内供体1ID：2ID的摩尔比为4：6至9：1，与（b ）有机铝化合物，并且任选地与（c）外电子给体化合物反应，所述方法在等于或高于78℃的温度下进行，并且通过使用有机铝化合物与固体催化剂组分的摩尔比 （b）:( a）低于5。
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公开(公告)号：EP2480606B1
公开(公告)日：2014-05-28
申请号：EP10745274.0
申请日：2010-08-26
发明人： GALVAN, Monica , CIARAFONI, Marco , COLLINA, Gianni , FUSCO, Ofelia , PANTALEONI, Roberto , MAZZUCCO, Antonio
CPC分类号： C08F297/083 , C08F110/06 , C08F210/06 , C08L23/12 , C08L23/16 , C08L2205/02 , C08L2207/02 , C08L2308/00 , C08L2314/02 , C08L2666/06 , C08F2500/04 , C08F2500/12 , C08F210/16 , C08F2500/17
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