摘要:
The invention relates to novel suspended chrome catalysts for the homopolymerization of ethylene and the copolymerization of ethylene and α-olefins, to a method for the production thereof and to the use thereof for the polymerization of olefins.
摘要:
Polyethylene composition with improved swell ratio and mechanical properties, particularly suited for preparing blow-moulded articles, said composition having the following features: 1) density from 0.945 to less than 0.952 g/cm 3 ; 2) ratio MIF/MIP from 15 to 30; 3) Shear-Induced Crystallization Index SIC from 2.5 to 5.5.
摘要翻译:所述组合物具有以下特征:1)密度为0.945至小于0.952g / cm 3;具有下列特征的组合物: 2)比例MIF / MIP从15到30; 3)剪切诱导结晶指数SIC为2.5〜5.5。
摘要:
Polyethylene composition with improved swell ratio and mechanical properties, particularly suited for preparing blow-moulded articles, said composition having the following features: 1) density from 0.945 to less than 0.952 g/cm 3 ; 2) ratio MIF/MIP from 15 to 30; 3) Shear-Induced Crystallization Index SIC from 2.5 to 5.5.
摘要:
New ethylene polymers having broad molecular weight distribution and long-chain branching, above all at high molecular weight fractions; the polymers have strain hardening equal or higher than 1.4 (at constant elongational rate of 0.5s -1 , at 150°C), branching index g' equal or lower than 0.9 (at Mw of 2⋅10 6 g/mol). The polymers are prepared by using a mixed catalyst system comprising a polymerization catalyst based on a late transition metal component having a tridentate ligand, and a Ziegler polymerization catalyst annealed at a temperature higher than 100°C, for a time of at least 10 minutes.
摘要:
Molding composition comprising polyethylene and having a density in the range from 0.915 to 0.955 g/cm3, an MI in the range from 0 to 3.5 g/10 min, an MFR in the range from 5 to 50, a polydispersity Mw/Mn in the range from 5 to 20, and a z-average moiar mass Mz of less than 1 million g/mol, a process for preparing such a composition, a catalyst suitable for the preparation of the same, as well as films comprising this molding composition.
摘要:
Monomodal copolymers of ethylene and molding compositions comprising such copolymers, wherein the copolymers have a density determined according to DIN EN ISO 1183-1, variant A in the range from 0.938 to 0.944 g/cm3, a melt index MFR21 determined according to ISO 1133 at 190°C under a load of 21.6 kg in the range from 12 to 17 g/10 min, a weight average molar mass Mw in the range from 140 000 g/mol to 330 000 g/mol, a polydispersity Mw /Mn in the range from 9 to 17, and a content of comonomer side chains per 1000 carbon atoms C x equal to or above a value defined via equation (I) Cx = 128.7 - 134.62 x d', wherein d' is the numerical value of the density of the copolymer in g/cm3, the use of the copolymers for producing injection-molded articles, as well as injection-molded articles comprising the copolymers, and process for the preparation of such monomodal copolymers.
摘要:
Monomodal copolymers of ethylene and molding compositions comprising such copolymers, wherein the copolymers have a density determined according to DIN EN ISO 1183-1, variant A in the range from 0.938 to 0.944 g/cm3, a melt index MFR21 determined according to ISO 1133 at 190°C under a load of 21.6 kg in the range from 12 to 17 g/10 min, a weight average molar mass Mw in the range from 140 000 g/mol to 330 000 g/mol, a polydispersity Mw /Mn in the range from 9 to 17, and a content of comonomer side chains per 1000 carbon atoms C x equal to or above a value defined via equation (I) Cx = 128.7 - 134.62 x d', wherein d' is the numerical value of the density of the copolymer in g/cm3, the use of the copolymers for producing injection-molded articles, as well as injection-molded articles comprising the copolymers, and process for the preparation of such monomodal copolymers.
摘要:
Molding composition comprising polyethylene and having a density in the range from 0.915 to 0.955 g/cm3, an MI in the range from 0 to 3.5 g/10 min, an MFR in the range from 5 to 50, a polydispersity Mw/Mn in the range from 5 to 20, and a z-average moiar mass Mz of less than 1 million g/mol, a process for preparing such a composition, a catalyst suitable for the preparation of the same, as well as films comprising this molding composition.
摘要:
Polyethylene which comprises ethylene homopolymers and/or copolymers of ethylene with 1- alkenes and has a molar mass distribution width MW/Mn of from 3 to 30, a density of from 0.945 to 0.965 g/cm3, a weight average molar mass Mw of from 50 000 g/mol to 200 000 g/mol, a HLMI of from 10 to 300 g/10 min and has from 0.1 to 15 branches/1000 carbon atoms, wherein the 1 to 15 % by weight of the polyethylene having the highest molar masses have a degree of branching of more than 1 branch of side chains larger than CH3/1000 carbon atoms, a process for its preparation, catalysts suitable for its preparation and also injection moldings in which this polyethylene is present.
摘要:
A polyethylene which comprises ethylene homopolymers and/or copolymers of ethylene with 1alkenes and has a molar mass distribution width Mme;/Mn of from 5 to 30, a density of from 0.92 to 0.955 g/cm3, a weight average molar mass Mme, of from 50000 g/mol to 500 000 g/mol and has from 0.01 to 20 branches/1000 carbon atoms and a z-average molar mass MZ of less than 1 Mio. g/mol, a process for its preparation, catalysts suitable for its preparation and also films in which this polyethylene is present.