Chalcogenide glass optical fibre
    41.
    发明公开
    Chalcogenide glass optical fibre 失效
    硫属化物玻璃光纤

    公开(公告)号:EP0849234A2

    公开(公告)日:1998-06-24

    申请号:EP98104164.3

    申请日:1996-03-06

    IPC分类号: C03C13/04

    摘要: A process for producing a preform for a chalcogenide glass fiber which comprises inserting a cladding tube having contained therein a chalcogenide glass rod for core into a quartz tube having at its bottom a nozzle having an aperture smaller than the outer diameter of the cladding tube, locally heating the bottom of the quartz tube and pulling the cladding tube having contained the glass rod for core and a process for producing a chalcogenide glass fiber by heating and drawing the preform thus obtained, by which processes the devitrification of glass and the generation of bubbles in the core glass or at the core glass-cladding glass interface can be prevented and the adhesion between the core glass and the cladding glass can be improved. In particular, when the glass material for core does not contain Ge, a chalcogenide glass fiber having such a core-cladding structure that the transmission loss of the glass fiber when infrared light pass through the fiber is small and the mechanical strength is high.

    摘要翻译: 一种硫属化物玻璃纤维用预成型体的制造方法,其特征在于,将具有芯用硫属化物玻璃棒的包覆管插入石英管内,在该石英管的底部具有孔径小于包层管外径的喷嘴, 加热石英管的底部并牵引包含芯用玻璃棒的包壳管,以及通过加热和拉拔由此获得的预成型物来制造硫属化物玻璃纤维的工艺,由此处理玻璃的失透和在 可以防止芯玻璃或芯玻璃包层玻璃界面,并且可以提高芯玻璃与包层玻璃之间的粘附性。 特别是在芯部用玻璃材料不含Ge的情况下,具有在红外光通过纤维时玻璃纤维的传输损失小,机械强度高的芯包层结构的硫属化物玻璃纤维。

    Gallium sulfide glasses
    43.
    发明公开
    Gallium sulfide glasses 失效
    Galliumsulphidgläser

    公开(公告)号:EP0775675A2

    公开(公告)日:1997-05-28

    申请号:EP97200367.7

    申请日:1995-03-27

    IPC分类号: C03C3/32 C03C13/04

    摘要: This invention is directed broadly to transparent glasses exhibiting excellent transmission far into the infrared region of the electromagnetic radiation spectrum, those glasses consisting essentially, expressed in terms of mole percent, of 40-80% Ga 2 S 3 , 0-35% RS x , wherein R is at least one network forming cation selected from the group consisting of aluminum, antimony, arsenic, germanium, and indium, 1-50% Ln 2 S 3 , wherein Ln is at least one cation selected from the group consisting of a rare earth metal cation and yttrium, 1-45% MS x , wherein M is at least one modifying metal cation selected from the group consisting of barium, cadmium, calcium, lead, lithium, mercury, potassium, silver, sodium, strontium, thallium, and tin, and 0-10% total chloride and/or fluoride. Glass compositions consisting essentially, expressed in terms of mole percent, of 5-30% Ga 2 S 3 , 0-10% R 2 S 3 , wherein R is at least one network forming cation selected from the group consisting of aluminum, antimony, arsenic, and indium, 55-94.5% GeS 2 , 0.5-25% MS x , wherein M is at least one modifying metal cation selected from the group consisting of barium, cadmium, calcium, lead, lithium, potassium, silver, sodium, strontium, tin, yttrium, and a rare earth metal of the lanthanide series, 0-10% total selenide, 0-25% total chloride and/or fluoride, and wherein the sulfur and/or selenium content can vary between 85-125% of the stoichiometric value when doped with Pr demonstrate exceptionally high values of τ.

    Gallium sulfide glasses
    44.
    发明公开
    Gallium sulfide glasses 失效
    硫化镓玻璃

    公开(公告)号:EP0775674A2

    公开(公告)日:1997-05-28

    申请号:EP97200366.9

    申请日:1995-03-27

    IPC分类号: C03C3/32 C03C13/04

    摘要: This invention is directed broadly to transparent glasses exhibiting excellent transmission far into the infrared region of the electromagnetic radiation spectrum, those glasses consisting essentially, expressed in terms of mole percent, of 40-80% Ga 2 S 3 , 0-35% RS x , wherein R is at least one network forming cation selected from the group consisting of aluminum, antimony, arsenic, germanium, and indium, 1-50% Ln 2 S 3 , wherein Ln is at least one cation selected from the group consisting of a rare earth metal cation and yttrium, 1-45% MS x , wherein M is at least one modifying metal cation selected from the group consisting of barium, cadmium, calcium, lead, lithium, mercury, potassium, silver, sodium, strontium, thallium, and tin, and 0-10% total chloride and/or fluoride. Glass compositions consisting essentially, expressed in terms of mole percent, of 5-30% Ga 2 S 3 , 0-10% R 2 S 3 , wherein R is at least one network forming cation selected from the group consisting of aluminum, antimony, arsenic, and indium, 55-94.5% GeS 2 , 0.5-25% MS x , wherein M is at least one modifying metal cation selected from the group consisting of barium, cadmium, calcium, lead, lithium, potassium, silver, sodium, strontium, tin, yttrium, and a rare earth metal of the lanthanide series, 0-10% total selenide, 0-25% total chloride and/or fluoride, and wherein the sulfur and/or selenium content can vary between 85-125% of the stoichiometric value when doped with Pr demonstrate exceptionally high values of τ.

    摘要翻译: 本发明广泛地指向透射玻璃,其在电磁辐射光谱的红外区域内显示出极好的透射性,这些玻璃基本上以40-80%Ga 2 S 3,0-35%RS x表示的摩尔百分比表示,其中R是 至少一种选自铝,锑,砷,锗和铟的形成阳离子的阳离子,1-50%Ln 2 S 3,其中Ln是至少一种选自稀土金属阳离子和钇的阳离子, 1-45%MSx,其中M为选自钡,镉,钙,铅,锂,汞,钾,银,钠,锶,铊和锡中的至少一种改性金属阳离子,以及0-10 总氯化物和/或氟化物。 主要由摩尔百分比表示的5-30%Ga 2 S 3,0-10%R 2 S 3组成的玻璃组合物,其中R是至少一种选自铝,锑,砷和铟的形成网络的阳离子,55 -94.5%GeS2,0.5-25%MSx,其中M为至少一种选自钡,镉,钙,铅,锂,钾,银,钠,锶,锡,钇和钇的改性金属阳离子 镧系元素的稀土金属,0-10%的总硒化物,0-25%的总氯和/或氟化物,并且其中当掺杂Pr时,硫和/或硒含量可以在化学计量值的85-125%之间变化 表现出特别高的τ值。

    Chalcogenide glass optical fibre, process for producing a preform therefor and process for drawing the fibre therefrom
    45.
    发明公开
    Chalcogenide glass optical fibre, process for producing a preform therefor and process for drawing the fibre therefrom 失效
    硫属化物玻璃,使得预成型体为预成型件和拉伸工艺的方法的光纤

    公开(公告)号:EP0731063A3

    公开(公告)日:1997-01-08

    申请号:EP96103472.5

    申请日:1996-03-06

    摘要: A process for producing a preform for a chalcogenide glass fiber which comprises inserting a cladding tube having contained therein a chalcogenide glass rod for core into a quartz tube having at its bottom a nozzle having an aperture smaller than the outer diameter of the cladding tube, locally heating the bottom of the quartz tube and pulling the preform compositing said cladding tube and glass rod for core through the nozzle of the said quartz tube. Also disclosed is a process for producing a chalcogenide glass fiber by heating and drawing the preform thus obtained, by which processes the devitrification of glass and the generation of bubbles in the core glass or at the core glass-cladding glass interface can be prevented and the adhesion between the core glass and the cladding glass can be improved. In particular, when the glass material for core does not contain Ge, a chalcogenide glass fiber having such a core-cladding structure that the transmission loss of the glass fiber when infrared light pass through the fiber is small and the mechanical strength is high.

    摘要翻译: 一种生产用于硫属化物玻璃纤维,其中含有插入包壳管的预成型件处理其中包含有用于核的硫属化物玻璃杆插入石英管具有在其底部的喷嘴具有孔径比包层管的外径小,在本地 加热石英管的底部并拉动所述预成型件通过所述石英管的喷嘴合成所述金属包层管和玻璃棒芯。 所以游离缺失盘是用于制造由加热硫族化物玻璃纤维和拉伸该预成型件这样得到的,通过其处理玻璃的失透和在芯玻璃或在芯玻璃包层玻璃界面气泡的产生可以防止过程和 芯玻璃和包层玻璃之间的粘附性能够得到改善。 特别是,当为芯玻璃材料不含锗,在研究了硫属化物玻璃纤维的芯 - 包层结构那样的玻璃纤维的传输损耗。当红外光通过光纤小,并且机械强度高。

    Gallium sulfide glasses
    47.
    发明公开
    Gallium sulfide glasses 失效
    硫化镓玻璃

    公开(公告)号:EP0676377A3

    公开(公告)日:1996-01-31

    申请号:EP95104460.1

    申请日:1995-03-27

    IPC分类号: C03C3/32 C03C13/04

    摘要: This invention is directed broadly to transparent glasses exhibiting excellent transmission far into the infrared region of the electromagnetic radiation spectrum, those glasses consisting essentially, expressed in terms of mole percent, of 40-80% Ga₂S₃, 0-35% RS x , wherein R is at least one network forming cation selected from the group consisting of aluminum, antimony, arsenic, germanium, and indium, 1-50% Ln₂S₃, wherein Ln is at least one cation selected from the group consisting of a rare earth metal cation and yttrium, 1-45% MS x , wherein M is at least one modifying metal cation selected from the group consisting of barium, cadmium, calcium, lead, lithium, mercury, potassium, silver, sodium, strontium, thallium, and tin, and 0-10% total chloride and/or fluoride. Glass compositions consisting essentially, expressed in terms of mole percent, of 5-30% Ga₂S₃, 0-10% R₂S₃, wherein R is at least one network forming cation selected from the group consisting of aluminum, antimony, arsenic, and indium, 55-94.5% GeS₂, 0.5-25% MS x , wherein M is at least one modifying metal cation selected from the group consisting of barium, cadmium, calcium, lead, lithium, potassium, silver, sodium, strontium, tin, yttrium, and a rare earth metal of the lanthanide series, 0-10% total selenide, 0-25% total chloride and/or fluoride, and wherein the sulfur and/or selenium content can vary between 85-125% of the stoichiometric value when doped with Pr demonstrate exceptionally high values of τ.

    摘要翻译: 本发明广泛地涉及在电磁辐射光谱的远红外区域具有优异透射性的透明玻璃,这些玻璃基本上由40-80%Ga 2 S 3,0-35%RSx表示的摩尔百分比表示,其中R是 至少一种选自铝,锑,砷,锗和铟的形成阳离子的阳离子,1-50%Ln 2 S 3,其中Ln是至少一种选自稀土金属阳离子和钇的阳离子, 1-45%MSx,其中M为选自钡,镉,钙,铅,锂,汞,钾,银,钠,锶,铊和锡中的至少一种改性金属阳离子,以及0-10 总氯化物和/或氟化物。 主要由摩尔百分数表示的5-30%Ga 2 S 3,0-10%R 2 S 3(其中R是至少一个选自铝,锑,砷和铟的形成阳离子的网状物)的组合物,55 -94.5%GeS 2,0.5-25%MS x,其中M是至少一种选自钡,镉,钙,铅,锂,钾,银,钠,锶,锡,钇和钇的改性金属阳离子 镧系元素的稀土金属,0-10%的总硒化物,0-25%的总氯和/或氟化物,并且其中当掺杂Pr时,硫和/或硒含量可以在化学计量值的85-125%之间变化 表现出特别高的τ值。