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51.发明公开
公开(公告)号：EP0187207A1
公开(公告)日：1986-07-16
申请号：EP85113186.2
申请日：1985-10-17
发明人： Graves, Daniel F.
IPC分类号： C01B35/06 , C01B21/098
CPC分类号： C01B21/0986 , C01B21/098 , C01B35/06
摘要： A compound described by the molecular formula: BNP 2 O 2 X 5 , wherein X is selected from the group consisting of P, Cl, Br, I and mixtures thereof and having the structure:
A process for its manufacture by reacting in a halogenated solvent a compound of the formula X 2 P(O)NHP(O)X 2 with a compound of the formula BX 3 , wherein X is selected from the class consisting of P, Cl, Br, l and mixtures thereof. Use thereof 2 as catalyst in the polymerisation of halophosphazene trimers and other oligomers.摘要翻译： 通过分子式：BNP 2 O 2 X 6描述的化合物，其中X选自P，Cl，Br，I及其混合物，并具有以下结构：...
...... 其制备方法 在卤代溶剂中使式X2P（O）NHP（O）X2的化合物与式BX3的化合物反应，其中X选自P，Cl，Br，I及其混合物。 其用途2作为卤代膦腈三聚体和其它低聚物聚合中的催化剂。 -
52.发明公开Method for purifying cyclic dichlorophosphazene trimer of catalytic impurities 失效一种用于净化催化杂质循环Dichlorphosphazentrimeren过程。
公开(公告)号：EP0185173A2
公开(公告)日：1986-06-25
申请号：EP85113702.6
申请日：1985-10-28
IPC分类号： C01B21/098 , C08G79/02
CPC分类号： C01B21/0986
摘要： Cyclic dichlorophosphazene trimer which is substantially pure except for catalytic impurities is purified by treating the trimer in the liquid phase with P 2 O 5 for 10-30 minutes at a temperature of 120-170°C. and atmospheric pressure, then subjecting the reaction mix to a single further purification step by sublimation, melt filtration, or distillation. The purified trimer will not polymerize in the absence of added catalyst at 300°C. or below.
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53.发明授权
公开(公告)号：EP0025850B1
公开(公告)日：1983-08-24
申请号：EP80104679.8
申请日：1980-08-08
IPC分类号： C01B21/098 , C08G79/02
CPC分类号： C01B21/098 , C01B21/0986
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54.发明授权Polymerization of inorganic element-containing monomers using plasma, and the formed product 无效使用等离子体的无机元素含单体的聚合和形成的产物
公开(公告)号：EP0019927B1
公开(公告)日：1982-09-29
申请号：EP80103029.7
申请日：1980-05-30
IPC分类号： C01B21/098 , C08F2/52 , C08G79/02 , C08G79/08 , C08G85/00
CPC分类号： C08F2/52 , C01B21/098 , C01B21/0986 , C08G79/025 , C08G85/00
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55.发明公开Method of purifying cyclic dichlorophosphazenes containing trace amounts of protic impurities 失效包括用于纯化含有的质子杂质痕迹环状dichlorophosphazenes方法。
公开(公告)号：EP0046584A1
公开(公告)日：1982-03-03
申请号：EP81106526.7
申请日：1981-08-21
IPC分类号： C01B21/098 , C08G79/02
CPC分类号： C01B21/0986
摘要： Cyclic dichlorophosphazenes containing trace amounts of protic impurities such as water are purified by treatment with boron trihalides under specified temperature and pressure conditions. The catalytic polymerization of the resultant cyclic dichlorophosphazenes, which are substantially free of protic impurities, is greatly improved.
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56.发明公开Process for the polymerization of cyclic polyhalophosphazenes using a catalyst composition of boron trihalide and oxygenated phosphorus compounds 失效一种用于使用由三卤化硼和氧化磷化合物的催化剂组合物的环状polyhalophosphazenes的聚合过程。
公开(公告)号：EP0025850A2
公开(公告)日：1981-04-01
申请号：EP80104679.8
申请日：1980-08-08
IPC分类号： C01B21/098 , C08G79/02
CPC分类号： C01B21/098 , C01B21/0986
摘要： Linear polydihalophosphazene polymers which are substantially free of gel are prepared by thermally polymerizing a cyclic polyhalophosphazene represented by the formula (NPX 2 ) 3 , wherein X is fluorine, chlorine or bromine in the presence of a catalyst which comprises the reaction product of a boron trihalide compound with an oxygenated phosphorus compound.
In addition to producing substantially gel free polymers, the catalyst composition of the process of the invention permits improved control of molecular weight, lower polymerization temperature, high rates of conversion of (NPCl 2 ), to (NPCl 2 ) n , and provides for more readily processible and derivatizable polymers.-
57.发明公开Polymerization of inorganic element-containing monomers using plasma, and the formed product 无效由此获得的含有无机元素，使用等离子体，并将产物单体的聚合。
公开(公告)号：EP0019927A1
公开(公告)日：1980-12-10
申请号：EP80103029.7
申请日：1980-05-30
IPC分类号： C01B21/098 , C08G79/02 , C08G79/08 , C08G85/00 , C08F2/52
CPC分类号： C08F2/52 , C01B21/098 , C01B21/0986 , C08G79/025 , C08G85/00
摘要： An ionized gas plasma is established in an electrical field in contact with a non-vapor volume monomer (liquid and/or solid). The plasma causes polymerization of the monomers which are of the phosphazene or carborane type.
摘要翻译： 电离气体等离子体是在电场中与非蒸气容积单体（液体和/或固体）接触建立英寸 等离子体使单体哪些是磷腈或碳硼烷类的聚合。
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公开(公告)号：EP0011117A1
公开(公告)日：1980-05-28
申请号：EP79103740.1
申请日：1979-10-02
申请人： ETHYL CORPORATION
CPC分类号： C01B21/0986
摘要： Linear phosphonitrilic chloride pleionomers having an average degree of polymerization of about 15 to 100 are conveniently prepared by heating linear phosphonitrilic chloride oligomers (e.g., (PNCl 2 ) 2-10 ) concurrently removing the phosphorus pentachloride vapors evolved. Heating temperatures of 275°C. -350°C and heating periods of from one to twenty and especially one to seven hours are used.
摘要翻译： 平均聚合度约为15-100的线性膦酰氯化物共聚物通过同时除去放出的五氯化磷蒸气的线性磷酰氯化物低聚物（例如，（PNCl 2）2-10）而方便地制备。 加热温度为275℃-350℃，加热时间为1至20℃，特别是1至7小时。
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公开(公告)号：EP0004877A1
公开(公告)日：1979-10-31
申请号：EP79100883.2
申请日：1979-03-23
IPC分类号： C08G79/02
CPC分类号： C01B21/098 , C01B21/0986
摘要： Thermal polymerization of (NPCl 2 ) 3,4 is improved by conducting the polymerization in the presence of Ziegler type catalysts, namely compounds of the transition metals: Ti, Zr, Hf, V, Nb, Ta, Cr, Mo or W, with or without the presence of compounds of B or Al as cocatalysts.
摘要翻译： （NPCI2）3,4的热聚合通过在齐格勒型催化剂即Ti，Zr，Hf，V，Nb，Ta，Cr，Mo或W的过渡金属化合物的存在下进行聚合而得到改善， 不存在B或Al的化合物作为助催化剂。
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