VERFAHREN ZUR ABSCHEIDUNG VON ETHYLENOXID AUS ABLUFT- ODER ABGASSTRÖMEN
    53.
    发明授权
    VERFAHREN ZUR ABSCHEIDUNG VON ETHYLENOXID AUS ABLUFT- ODER ABGASSTRÖMEN 失效
    工艺用于乙烯的提取及废气流的分离

    公开(公告)号:EP0744990B1

    公开(公告)日:1997-10-29

    申请号:EP95908216.5

    申请日:1995-01-27

    IPC分类号: B01D53/86 B01D53/72 A61L2/20

    摘要: Ethylene oxide is removed from exhaust gases of sterilisation plants and/or from outgoing air from storehouses for sterilised products. A catalyst-containing adsorbent (for example active coal or silica gel) binds the ethylene oxide, forming glycol. Two or more adsorptive filters (4a, 4b) allow the outgoing air to be cleaned without interruption, as the filters are alternatively switched off and regenerated. Regeneration is carried out by extracting the adsorbent with a liquid (for example boiling water). A gas wash may be used as a pre-washing process, an ethylene oxide concentration of about 15 mg/m3 being achieved in the washing gas and residual amounts lower than 1 mg/m3 being then ensured in the adsorber. The glycol contained in the waste water from the pre-washing process may be decomposed into CO¿2? and H2O in a downstream biological trickling reactor (7). The ethylene oxide-free pure air from the installation is used for aerating the biological trickling reactor (7)

    A GAS PURIFYING METHOD AND APPARATUS
    54.
    发明授权
    A GAS PURIFYING METHOD AND APPARATUS 失效
    方法和装置的尾气处理系统

    公开(公告)号:EP0644795B1

    公开(公告)日:1997-05-28

    申请号:EP93900494.1

    申请日:1992-12-18

    发明人: THUNSTRÖM, Alf

    IPC分类号: B01D53/72 B01D53/74

    CPC分类号: B01D53/885 B01D53/864

    摘要: This invention relates to a method of purifying gases which are polluted by hydrocarbons and the like in an apparatus comprising two reactors, each reactor comprising a catalyst bed and a ceramic bed. According to the invention the method is characterized by the combination of the following moments: the gas that shall be purified is forced to stream alternately through a passage comprising the first reactor (1) and the second reactor (2) (clockwise streaming) and the second reactor (2) and the first reactor (1), respectively (counterclockwise streaming), the purification of the gas is made by the fact that the hydrocarbons in the gas are oxidized to carbon dioxide and water in the catalysts (5, 6); the temperature of the gas streaming through the reactors (1, 2) is measured and when the temperature exceeds a certain level, a portion of the gas is taken out from the apparatus during the passage of the catalyst bed (5) of the second reactor (2) if the gas streams in a clockwise direction, whereas a portion of the gas is taken out from the apparatus during the passage of the catalyst bed (4) of the first reactor (1), if the gas streams in a counterclockwise direction. The invention also relates to an apparatus which is useable for carrying out the method.

    Wabenförmiger keramischer Katalysator zur Oxidation von Kohlenwasserstoffen und halogenierten Kohlenwasserstoffen
    59.
    发明公开
    Wabenförmiger keramischer Katalysator zur Oxidation von Kohlenwasserstoffen und halogenierten Kohlenwasserstoffen 失效
    Wabenförmigerkeramischer Katalysator zur Oxidation von Kohlenwasserstoffen und haloierten Kohlenwasserstoffen。

    公开(公告)号:EP0640391A2

    公开(公告)日:1995-03-01

    申请号:EP94112111.3

    申请日:1994-08-03

    申请人: TRIDELTA GmbH

    摘要: Durch die Erfindung soll eine Katalysator zur oxidativen Entgiftung auch von Spuren der oben genannten Stoffgruppe geschaffen werden, der die Nachteile bekannter Katalysatoren mit Metallen der Platingruppe hinsichtlich Preis, erforderlicher Regelungstechnik und Empfindlichkeit gegen abrasive Stäube nicht aufweist. Diese Aufgabe wird bei einem wabenförmigen keramischen Katalysator durch die Kombination folgender Merkmale gelöst:

    Trägerkomponente aus Schichtsilikaten,
    gleichmäßig zugemischte ternäre Oxide als katalytisch wirksame Komponente,
    spezifische Oberfläche > 50 m²/g
       und
    bimodale Porengrößenverteilung zwischen 5 ... 10 nm und 25 ... 200 nm.

    摘要翻译: 本发明是为了产生氧化解毒的催化剂,即使是上述物质组的痕迹,其价格,所需的控制方法和对研磨性粉尘的敏感度也不表现出含有铂族金属的已知催化剂的缺点。 该目的通过以下特征的组合在蜂窝状陶瓷催化剂中实现: - 由硅酸盐制成的载体组分, - 均匀混合的三元氧化物作为催化活性组分,比表面积> 50m 2 / g, - 5〜10nm和25〜200nm之间的双峰孔径分布。