PROCESSES FOR SYNTHESIS OF 1,3,3,3-TETRAFLUOROPROPENE AND 2,3,3,3-TETRAFLUOROPROPENE
    71.
    发明公开
    PROCESSES FOR SYNTHESIS OF 1,3,3,3-TETRAFLUOROPROPENE AND 2,3,3,3-TETRAFLUOROPROPENE 有权
    方法合成的1,3,3,3-四氟丙烯和2,3,3,3-四氟丙烯

    公开(公告)号:EP1740520A1

    公开(公告)日:2007-01-10

    申请号:EP05742279.2

    申请日:2005-04-29

    摘要: Disclosed in one embodiment is a process for the synthesis of 1,3,3,3-tetrafluoropropene that comprises (a) reacting a compound of formula (I) X1X2 with a compound of formula (II) CF3CH=CH2 to produce a reaction product comprising a compound of formula (III) CF3CHX1CH2X2, wherein X1 and X2 are each independently selected from the group consisting of hydrogen, chlorine, bromine and iodine, provided that X1 and X2 are not both hydrogen; (b) when X2 in formula (III) is not fluorine, fluorinating the compound of formula (III) to produce a reaction product comprising a compound of formula (III) wherein X1 is as described above and X2 is fluorine; and (c) exposing said compound of formula (III) to reaction conditions effective to convert said compound to 1,3,3,3,-tetrafluoropropene. In another embodiment, the process comprises (a) reacting chlorine with a compound of formula (I) CH3CH=CH2 to produce a reaction product comprising a compound of formula (II) CCI3CHC1CH2C1; (b) fluorinating the compound of formula (II) to produce a reaction product comprising a compound of formula (III) CF3CHC1CH2F; and (c) exposing said compound of said formula (III) to reaction conditions effective to convert said compound to 1,3,3,3-tetrafluoropropene.

    Verfahren zur Herstellung von 1,3-Dichlorpropan
    79.
    发明公开
    Verfahren zur Herstellung von 1,3-Dichlorpropan 有权
    一种用于1,3-二氯丙烷的制备方法

    公开(公告)号:EP1067105A2

    公开(公告)日:2001-01-10

    申请号:EP00108356.7

    申请日:2000-04-15

    IPC分类号: C07C19/01 C07C17/361

    摘要: Die Erfindung betrifft ein Verfahren zur Herstellung von 1,3-Dichlorpropan durch Umsetzung von Bis(3-hydroxypropyl)ether mit Chlorwasserstoff, gegebenenfalls in Gegenwart von tertiären basischen Stickstoffverbindungen oder anderen tertiären aliphatischen Basen als Katalysatoren, Abdestillation des 1,3-Dichlorpropans und des Reaktionswassers und Aufarbeitung der beiden Phasen.

    摘要翻译: 本发明涉及一种通过二(3-羟基丙基)醚与氯化氢的反应制备1,3-二氯丙烷,任选叔碱性氮化合物或其它叔脂族碱作为催化剂的存在下,蒸馏除去1,3-二氯丙烷和 反应和工作了两个阶段的水。