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    PHOSPHACYCLE-CONTAINING LIGAND FOR CHROMIUM COMPLEX AND OLEFIN OLIGOMERISATION CATALYST THEREFROM
    10.
    发明公开
    PHOSPHACYCLE-CONTAINING LIGAND FOR CHROMIUM COMPLEX AND OLEFIN OLIGOMERISATION CATALYST THEREFROM 审中-公开

    公开(公告)号：EP3453452A3

    公开(公告)日：2019-06-05

    申请号：EP18172724.9

    申请日：2016-03-10

    申请人： DOW GLOBAL TECHNOLOGIES LLC

    发明人： KLOSIN, Jerzy ,  MILBRANDT, Kara A. ,  BOELTER, Scott D. ,  WILSON, David R. ,  ROSEN, Mari S. ,  WELSH, Dean M. ,  MARGL, Peter M. ,  KOH, Kyoung Moo ,  PEARSON, David M. ,  HUACUJA, Rafael

    IPC分类号： B01J31/24 ,  B01J31/18 ,  B01J31/14 ,  C07C2/36 ,  C07C2/30 ,  C07F9/6568

    摘要： The present invention relates to a composition comprising a phosphacycle-containing ligating compound represented as:

    wherein:
    P is phosphorus; X 1 is phosphorus; each of R 1 and R 2 is independently a substituted or
    unsubstituted hydrocarbon derivative, a substituted or unsubstituted heterohydrocarbon derivative, or a substituted or unsubstituted heteroatom group having from one to 50 non-hydrogen atoms; m is 1; R 1 and R 2 are linked together to form a divalent moiety represented as

    which together with P forms a cyclic structure (phosphacycle) containing from 3 to 10 ring atoms; each of R 3 and R 4 is independently hydrogen, halogen, a substituted or unsubstituted hydrocarbon derivative, a substituted or unsubstituted heterohydrocarbon derivative, or a substituted or unsubstituted heteroatom group having from one to 50 non-hydrogen atoms; R 3 and R 4 are optionally linked together to form a divalent moiety represented as

    wherein the optional character of the linkage is depicted by a dashed connection, which together with X 1 forms a cyclic structure containing from 3 to 10 ring atoms; Y is a divalent linking group [L(R 5 ) q ] p between P and
    X 1 containing from one to 50 non-hydrogen atoms; [L(R 5 ) q ] p is represented by:

    wherein each L is independently selected from the group consisting of nitrogen; p is an integer number from 1 to 6; R 5 is independently hydrogen, halogen, substituted or unsubstituted hydrocarbon derivative, substituted or unsubstituted heterohydrocarbon derivative, or a substituted or unsubstituted heteroatom group; q is 0, 1, or 2; provided that the [L] p subunit of the divalent linking group [L(R 5 ) q ] p does not comprise an amidine (N-C=N) group; further provided that in at least one phosphacycle of the phosphacycle-containing ligating compound, both atoms directly bonded to P or X 1 are sp 3 hybridized; still further provided that one or two phosphacycles comprising P, R 1 , and R 2 , or comprising X 1 , R 3 , and R 4 , contain no P-N, P-O, or P-S bonds within the ring part of the phosphacycle; two R 5 groups attached to the same L atom may be optionally linked together to form a cyclic structure that contains from 3 to 10 ring atoms; from two to ten independently selected ligating compounds may be optionally linked together via their respective independently selected Y, R 1 , R 2 , R 3 , R 4 or R 5 groups to form a poly(ligating compound) species, and wherein the composition is not 8-aza -1-phosphatricylo[3.3.0.0 2,6 ]octane.